1) transition dipole moment
跃迁偶极矩
1.
The transition dipole moments of two compounds were determined,the measured value being 7.
以对硝基苯胺、苯胺、5 氨基嘧啶和N,N 二羟乙基苯胺为原料通过两步重氮化-偶合反应合成了两种给体-受体型非线性光学偶氮分子,用红外光谱、核磁共振、熔点、紫外光谱进行了表征,测定了分子的跃迁偶极矩,两个化合物的跃迁偶极矩分别为7 12D和8 76D,它们在不同极性溶剂中表现出明显的溶致变色效应,紫外吸收最大位移分别达到20nm和15nm。
2.
The transition dipole moment of these compounds is determined.
测定了化合物的跃迁偶极矩 ,并研究了化合物的溶致变色效应。
3.
The properties of the electronic transition dipole moment of Pt(100) have been investigated using H/Pt n δ (δ=0,-1) clusters and the single-exciton configuration interaction.
5nm入射激发光时 ,桥位和穴位吸附的电子跃迁偶极矩和振子强度都很小 ,因而 Raman信号太弱 ,不能检测到 ;只有在高覆盖度下的氢顶位吸附 ,才能检测到 Raman信号。
2) dipole transition moment
偶极跃迁矩
1.
Ar(~3P_(0,2))] with SOCl_2 by usingdischarge-flowing after glow technique, which was assigned to the transition of pro-duct SO(A-X), Based on analyses of the spectrum intensities, it was found thatdipole transition moment changed with r-centroids, and the relation of changewas obtained by least squares fitting.
对光谱强度分析表明:SO(A→X)的偶极跃迁矩Re随核间距明显地变化。
3) dipole transition matrix element
偶极跃迁矩阵元
4) dipole transition
偶极跃迁
1.
Some important special cases, such as the average value of the integer power of radial vector, the matrix element of the electric dipole transition and the element of the electric quadrupole transition, are obtained from the general formula.
根据广义Laguerre多项式的数学性质,导出了较为简单的二维各向同性谐振子径向矩阵元的普遍公式,并在这基础上计算了一些重要特殊情形的径向矩阵元:矢径ρ整数次幂的平均值,电偶极跃迁矩阵元和电四极跃迁矩阵元。
5) electric dipole transition
电偶极跃迁
1.
Discussion on universal applicable selection rule of electric dipole transition;
关于电偶极跃迁的普用选择定则的讨论
2.
Only cohen the symmetry of integrated function in integral of electric dipole transition moment is allowed, can the transition metal complexes show colour.
讨论了导致过渡金属配合物显色的二种电子跃迁过程，只有当电偶极跃迁矩积分的被积函数的对称性允许时，才有可能产生颜色；分裂能的差别，导致跃迁能的不同，因而呈现出不同的视色。
补充资料：“质子-电子偶极-偶极”质子弛豫增强
“质子-电子偶极-偶极”质子弛豫增强
物理学术语。原子核外层中不成对的电子质量小，但磁动性很强，可使局部磁场波动增强，促使氢质子弛豫加快，从而使T1和T2缩短，这种效应即为PEDDPRE。过渡元素和镧系元素大部分在d和f轨道有多个不成对电子，所以其离子往往具有PEDDPRE，可用来作顺磁性对比剂，如钆(Gd)。Gd在外层有7个不成对电子，具有很强的顺磁性。
说明：补充资料仅用于学习参考，请勿用于其它任何用途。
参考词条