1) intramolecular coordination
分子内配位
2) intramolecular five-coordination
分子内五配位
3) coordination supramolecule
配位超分子
1.
Synthesis,crystal structure and spectral analysis of 1D double-chain Mn(Ⅱ) coordination supramolecule bridged by o-phthalic acid;
邻苯二甲酸桥联的一维双链锰配位超分子的合成、晶体结构及光谱分析
2.
Three Mn(Ⅱ) coordination supramolecules Mn(2,5-dcp)2(H2O)2 (1),Mn(INA)2(H2O)4 (2) and Mn(phen)2Cl2 (3) were synthesized by hydrothermal method (2,5-dcp=pyridine-2,5-dicarboxylic acid,INA= iso-nicotinic acid,phen=1,10-phenanthroline).
采用水热合成方法得到了三种Mn(Ⅱ)配位超分子:Mn(2,5-dcp)2(H2O)2(1),Mn(INA)2(H2O)4(2)和Mn(phen)2Cl2(3)(2,5-dcp=pyridine-2,5-dicarboxylic acid,INA=iso-nicotinic acid,phen=1,10-phenanthroline)。
4) coordination polymer
配位高分子
1.
The coordination polymer ｛Zn 3(Ac) 4(4,4′ bpy) 3[N(CN) 2] 2} n is prepared and characterized by X\|ray diffraction.
合成了配位高分子 {Zn3(Ac) 4 (4,4′ bpy) 3[N(CN) 2 ]2 } n,并用X射线衍射表征了其结构 ,结构包含一个独特的三腿梯子。
2.
Recently the employment of pre-designed and functional bi- or polynuclear units as building blocks to construct coordination polymers, especially low-dimensional polymers, is an attractive road to functional materials, in which way the reaction condition is quite mild and the control of product is easy to achieve, and also synthetic materials may posses.
近些年来,利用双核或多核金属配合物作为“结构单元”构建配位高分子,特别是低维配位高分子,已成为一种非常引人注目的制备功能材料的途径。
5) molecule coordination number
分子配位数
1.
In this article, the importance of the temperature dependence of molecule coordination numbers in establishing local composition models has been studied.
本文通过统计力学理论对分子配位数与温度之间的函数关系在建立局部组成模型中的重要性进行探讨,发现早期局部组成模型中(诸如Wilson、NPTL方程等)分子配位数作为恒定常数的假设不太合理,这一不合理假设导致了这些模型不能满足第二维里系数对组成的二次依赖性等理论缺陷,从而限制了这些模型对低密度流体混合物的应用。
6) coordinated water molecule
配位水分子
1.
Four SBUs(Secondary Building Units), containing controllable coordinated water molecules, and eleven coordinations were synthesized.
两个体系共合成了4个含可控制性配位水分子的SBUs(Secondary Building Units)和11个二次合成配合物,测定了这15个配合物的晶体结构并进行了元素分析、IR、和单晶X-射线衍射等结构表征,初步分析了这15个配合物的磁学性质,很好地解释了结构-磁性间的关系。
补充资料：内位
1.皇后之位。亦指皇后。
说明：补充资料仅用于学习参考，请勿用于其它任何用途。
参考词条