1) [1,5]-Hydrogen migration
[1,5]氢迁移
2) [1,5] PrS migration
[1,5]PrS-迁移
3) inner hydrogen atom transfer
内氢迁移
1.
The transition states were found and opti- mized, and the differences between rates of inner hydrogen atom transfer (IHAT) reactions were presented.
在确定各反应体系反应物、产物稳定构象的基础上,采用B3LYP/6-31G**方法在Gaussian03程序下,对质子化的双氧/硫杂卟啉的内氢迁移(IHAT)反应进行研究,寻找并优化相应的过渡态,比较其迁移反应速率的差异。
4) Hydrogen-migration
氢迁移
1.
The IRC Analysis of Uninolecular Reaction:(Ⅱ)The Change of the Net Charge along IRC in the Hydrogen-migration Reaction of Formamide;
单分子反应IRC解析（Ⅱ）─甲酰胺氢迁移中的电荷变化
2.
The IRC Analysis of Unimolecular Reaction: (Ⅰ) The Geometric Parameters and FMO in the Hydrogen-migration Reachon of Formamide;
单分子反应IRC解析──Ⅰ甲酰胺氢迁移反应的几何参数和FMO
5) Aromatic Radical
芳香1,5-氢转移
1.
Aromatic Radical-Induced Intramolecular Aromatic 1,5-Hydrogen Transfer;
设计合成了一系列的4-苯氧(硫)基-3-氨基-1,8-萘酐及其衍生物的重氮盐5a-h,并且它们在普朔尔环化反应时都生成了相对应的两个五元环和六元环的异构体9a-h和10a-h,证明了在该体系中存在着芳香自由基诱导的芳香1,5-氢转移的现象。
6) H-transfer reaction
氢迁移反应
1.
DFT study on the H-transfer reaction of conjugated trans-CH_2CH—CHC∶LiF;
反式共轭类碳烯CH_2CH—CHC∶LiF氢迁移反应的DFT研究
2.
H 2CCLiF has two equilibrium structures, but only one can exist, the structure is as following: The transition-state of intra-molecular H-transfer reaction of the above structure has been determined, and the average lifes of H 2CCLiF at different temperatures have been obtained to be τ=7.
对稳定的平衡结构 ,找到了分子内氢迁移反应的过渡态 ,并计算了不同温度下不饱和类卡宾H2 CCLiF的平均寿命τ,在 2 0 0K时 ,τ =7。
补充资料：(OC-6-11)-二氢六氢铂酸
CAS: 16941-12-1
分子式: H2PtCl6·6H2O
分子质量: 517.92
熔点: 60℃
中文名称: 氯铂酸；(OC-6-11)-二氢六氢铂酸
英文名称: hexachloro-, dihydrogen, (OC-6-11)-Platinate；Chloroplatinic acid；chloroplatinic acid；dihydrogen hexachloroplatinate；dihydrogen hexachloroplatinate
性质描述: 红褐色结晶
分子式: H2PtCl6·6H2O
分子质量: 517.92
熔点: 60℃
中文名称: 氯铂酸；(OC-6-11)-二氢六氢铂酸
英文名称: hexachloro-, dihydrogen, (OC-6-11)-Platinate；Chloroplatinic acid；chloroplatinic acid；dihydrogen hexachloroplatinate；dihydrogen hexachloroplatinate
性质描述: 红褐色结晶
说明：补充资料仅用于学习参考，请勿用于其它任何用途。
参考词条