1)  Iridium complex
Ir配合物
2)  IR
IR
1.
Syntheses of IrO_x-TiO_2 Nano-powers from TiN via Impregnation-thermal Decomposition Method and Its Characterization;
TiN浸渍-热分解法制备IrO_x-TiO_2粉体催化剂及其表征
2.
Study and application for microwave-assisted digestion technique for analysis of Pt Pd Rh Ir in precious metal alloys;
微波消解技术在难处理贵金属合金PtPdRhIr分析中的研究与应用
3.
Analysis for intermediate and by-product of crystal violet lactone with IR and NMR;
IR和NMR法对结晶紫内酯中间体及其副产物的分析
3)  iridium
Ir
1.
Interdiffusion problem of iridium/rhenium was studied during preparation of iridium/rhenium thruster.
在电子探针测量的基础上,根据扩散理论和Ir-Re相图数据,建立了一个全新的Ir/Re两相扩散模型。
2.
The superficial characteristics of iridium-doped gold jewelry and the occurrence and the chemical compositions of doped material in gold jewelry have been investigated by using optical microscopy and X-ray fluorescence spectrum analysis.
采用显微镜和X射线荧光光谱分析方法对掺Ir黄金饰品的外观特征、掺入物的化学成分、存在形式等进行了研究。
3.
The progress in the research of iridium-coated rhenium thruster nozzle prepared by chemical vapor deposition(CVD) is reviewed in this paper.
Re/Ir发动机是美国研制成功的应用于空间飞行器的第三代高性能发动机。
4)  Ir(Ⅳ)
Ir(Ⅳ)
5)  IR spectra
IR谱
1.
The vibrational frequencies,the IR spectra and the thermodynamics properties in different temperatures of the system were obtained on the basis of vibrational analysis, the relations of the effects of temperatures on thermodynamics properties were also obtained.
用B3LYP法,在6-31G(d,p)基组水平上计算4,6-双-(5-氨基-3-硝基-1,2,4-三唑-1-基)-5-硝基嘧啶(DANTNP)的性能,得其稳定的几何构型和键级;在振动分析的基础上求得体系的振动频率、IR谱及不同温度的热力学性质及温度对热力学性能影响的关系式。
2.
The vibrational frequencies,the IR spectra and the thermodynamics properties in different temperatures of the system were obtained on the basis of vibrational analysis,the relations of the effects of temperatures on thermodynamics properties were also obtained.
用B3LYP法,在6-31G(d,p)基组水平上计算二硝基吡唑并吡唑(DNPP)的性能,得其稳定的几何构型、分子轨道及键级;在振动分析的基础上求得体系的振动频率、IR谱及不同温度下的热力学性质,并得温度对热力学性能影响的关系式;用Monte-Carlo方法从理论上计算密度,运用Kamlet公式预测爆速。
3.
The full geometry optimization of N_(20)and IR spectra are performed using nonlocal density functional theory (DFT) method.
基于简谐振动分析求得IR谱频率,运用统计热力学方法,求得其在298~1500K的热力学性质C0p,m、S0m和H0m,还比较了N20分子和富勒烯的分子静电势图。
6)  FT-IR
FT-IR
1.
Investigation on UV curing reaction of dicyclopentadienyl acrylate by FT-IR;
丙烯酸双环戊二烯酯在UV固化反应中的FT-IR研究
2.
FT-IR and GC-MS Study on the Gas Solid Phase Photocatalysis of DECP over Nano-TiO_2;
DECP在纳米TiO_2上气-固相光催化的FT-IR和GC-MS研究
3.
Electrical Conductivity and FT-IR Spectrum of Microemulsion HEHEHP Saponified with Ammonia;
氨皂化的P507微乳液导电行为及FT-IR光谱研究
参考词条
补充资料:外轨配合物和内轨配合物
      根据L.C.鲍林的价键理论,具有八面体结构并有4个未成对电子的、顺磁性的[CoF6]3-,或有5个未成对电子的、顺磁性的[Fe(H2O)6]3+,其配位成键杂化轨道为4s4p34d2,所用d 轨道与s和p轨道是属于同一主能级的。这类具有nsnp3nd2形式的配合物(见配位化合物), 因为使用了外层的d轨道,所以叫做外轨配合物。两种配合物的杂化成键轨道分别如图所示。对于具有八面体结构且所有电子都是成对的、抗磁性的[Co(NH3) 6]3+, 或具有1个未成对电子的、 顺磁性的[Fe(CN)6]3-,其成键杂化轨道为3d24s4p3,使用了比s和p轨道低一级主能级层中的d轨道。这类具有(n-1)d2nsnp3型式的配合物,由于使用了内层的d轨道,所以叫做内轨配合物。
  
  在四配位体系中,具有四面体结构且有两个未成对电子的顺磁性的[NiCl4] 2-,其成键杂化轨道为4s4p3,属外轨配合物。而所有电子都成对的、抗磁性的[Ni(CN)4]2-,其成键杂化轨道为3d4s4p2,是平面正方形结构,属内轨配合物。两种配合物的杂化成键轨道如图所示。
  

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