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1)  hydrophilic macromolecule
大分子亲水单体
1.
High solid content and stable soap-free emulsion of styrene(St) and butylacrylate(BA) was prepared in the presence of ionic hydrophilic monomer,nonionic hydrophilic macromolecule and amphiphilic monomer.
利用离子型小分子亲水单体和非离子型大分子亲水单体与两亲性单体共同参与共聚的无皂乳液聚合,制备了高固含、稳定的苯-丙乳液。
2)  hydrophilic macromonomer
亲水性大分子单体
1.
The concept of macromonomer and the synthesis of hydrophilic macromonomer were introduced in this article, accompanied with the discussion on the application of macromonomer in graft copolymer, block polymer, polymeric nanosphere, biochemistry and medicine field.
阐述了自由基聚合、原子转移自由基聚合、生物合成等亲水性大分子单体合成方法,介绍了聚乙烯吡啶等一些重要的亲水性大分子单体的合成,论述亲水性大分子单体在聚合物分子设计和改性方面的作用及在合成接枝聚合物、嵌段聚合物、高分子纳米微球和生命科学及医学领域中的应用。
3)  large hydrophilic molecular
亲水性大分子
1.
Promoting mechanism of enhancers and transport pathway of large hydrophilic molecular across nasal epithelium studied by ESR and CLSM technologies;
ESR和CLSM技术用于促渗剂作用机制及亲水性大分子跨鼻黏膜转运途径的研究
4)  hydrophilic monomer
亲水单体
1.
As a hydrophilic monomer in WPU synthesis,further study on the oligomers of polyether and polyester with sulphonate group was worthy.
小分子磺酸盐熔点高、脂溶性小,仅N-(2-氨基乙基)-氨基乙烷磺酸钠(AAS)在实际生产中得到应用,含磺酸盐基团的聚醚和聚酯低聚物作为WPU合成的亲水单体值得深入研究。
2.
Cross-linked Copolymer gels were successfully prepared by copolymerization of long alkyl chain acrylic ester (hexadecyl acrylate(HA), octadecyl acrylate(ODA),) and hydrophilic monomer (acrylic acid(AA), methacrylic acid(MAA), 2-hydroxy-ethyl ester(HEA)) , using absolute ethanol as a solvent, N,N' -methylene-bis-acrylamide (MBAA) as a cross-linking agent at 50@.
合成了丙烯酸长链酯(丙烯酸十六酯(HA)、丙烯酸十八酯(ODA))与亲水单体(丙烯酸(AA)、甲基丙烯酸(MAA)、丙烯酸羟乙酯(HEA))的共聚物凝胶,研究了共聚组成对共聚物凝胶性能的影响。
3.
The water-borne technology for polyester is reviewed with using different hydrophilic monomers, including trimellitic anhydride, dimethylmalonic acid, UV curable hyperbranched waterborne polyester, as well as sulphonate monomer.
综述了4种含有不同亲水单体的聚酯水性化技术,包括传统型的以偏苯三酸酐为亲水性单体的水性聚酯、二羟甲基丙酸为亲水性单体的水性聚酯、紫外固化超支化水性聚酯以及磺酸盐型单体的水性聚酯。
5)  macromonomer
大分子单体
1.
Synthesis of macromonomer by atom transfer radical polymerization and its application to preparing polymeric microspheres;
ATRP法合成大分子单体及其在微球制备中的应用
2.
Preliminary study on the graft copolymers of poly(D,L-lactide) macromonomers and N-vinyl pyrrolidone;
PLA大分子单体与NVP接枝共聚物的初步研究
3.
Synthesis and characterization of mono-capped polyurethane-acrylate macromonomer with a vinyl group
双键单封端聚氨酯丙烯酸酯大分子单体的合成及表征
6)  Macromer
大分子单体
1.
Amphiphilic poly(vinyl pyridine)(PVP) with uniform polyoxyethylene(PEO) was synthesized by copolymerization of the PEO macromer with 2-vinyl pyridine in benzene,using AIBN as initiator.
用聚氧乙烯(PEO)大分子单体与2-乙烯基吡啶(VP)在苯中以偶氮二异丁腈为引发剂共聚,合成了带规整聚氧乙烯(PEO)支链的聚2-乙烯基吡啶(PVP)。
2.
The polymer- polyol- dispersions have been synthesized by using free radical copoly- merization of the macromers and styrene/acrylonitrile.
利用大分子单体法合成了聚合物聚醚多元醇 。
3.
Copolymerization conditions of w-methacryloyl polyoxyethylene macromers with methyl(MMA)in benzene using AIBN as initiator was studied.
本工作研究了末端为甲基丙烯酸酯型的聚环氧乙烷(PEO)大分子单体与甲基丙烯酸甲酯(MMA)溶液自由基共聚反应。
补充资料:大分子单体
分子式:
CAS号:

性质:简称大单体。带有可聚合端基的线型聚合物,一般分子量在1000~2000左右,分子量分布窄。可由负离子聚合、正离子聚合、基团转移聚合、自由基聚合及缩聚等制备。可聚合端基有苯乙烯基、烯丙基、甲基丙烯酰基、环氧基、噁唑啉基等。大分子单体与一般单体共聚,可得到支链长短很规整的接枝共聚物。大分子单体的共聚物或均聚物常被称为梳状聚合物。

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