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1)  rearranged drimane
重排补身烷
1.
In these bicyclic sesquiterpanes,the relative abundance of the rearranged drimane is regularly changed in spatial distribution,which may indicate the characteristics of petroleum migration and accumulation in QHD32-6 oilfield.
该油田双环倍半萜中重排补身烷的相对丰度在纵向上和横向上都表现出有规律的变化,这种规律性的变化可能反映了秦皇岛32-6油田油气运移与聚集的特征。
2.
The distributional characters of bicyclic sesquctecpances show that rearranged drimanes are relatively rich in the samples in Region A and relatively poor in Region C, but drimanes are relatively poor in Region A and rich in Region C.
双环倍半萜分布特征显示 ,A区原油重排补身烷含量相对较高 ,C区原油补身烷含量相对较高 ,这一特征与塔里木盆地海相和湖相原油特征相一致 ,暗示南海A、C区原油可能属不同成因类型 ;这一特征与其原油分子组成的非均质性在油区内的变化颇具一致性。
2)  homodrimane
升补身烷
3)  drimane
补身烷
1.
The distributional characters of bicyclic sesquctecpances show that rearranged drimanes are relatively rich in the samples in Region A and relatively poor in Region C, but drimanes are relatively poor in Region A and rich in Region C.
双环倍半萜分布特征显示 ,A区原油重排补身烷含量相对较高 ,C区原油补身烷含量相对较高 ,这一特征与塔里木盆地海相和湖相原油特征相一致 ,暗示南海A、C区原油可能属不同成因类型 ;这一特征与其原油分子组成的非均质性在油区内的变化颇具一致性。
4)  diasteranes
重排甾烷
1.
The GC/MS analyses for alkanes from Late Jurassic source rocks of the Liudong depression,Kailu Basin,northeastern China showed that the concentration of diasteranes in some samples decreases anomalously with depth,suggesting that in this case the formation of these compounds may be not depended on maturity.
陆东凹陷上侏罗统生油岩样品饱和烃色质分析表明,重排甾烷随井深出现含量下降的逆转现象,表明热演化不完全是这类化合物形成的主要控制因素。
5)  alkyl rearrangement
γ-烷基重排
1.
An γ - alkyl rearrangement of an alkyl group in phosphonate is also found during electron impacting.
发现3-取代芳基-2-吲哚基膦酸酯的膦酰基中的烷基在碎裂过程中也产生γ-烷基重排反应,同时讨论了这类化合物的质谱碎裂行为。
6)  rearranged hopanes
重排藿烷类
1.
Composition and origin approach of rearranged hopanes in Jurassic oils of cen tral Sichuan basin;
川中侏罗系原油重排藿烷类化合物的组成及成因探讨
补充资料:[2,3]维蒂希重排
分子式:
CAS号:

性质:烯丙基芳甲基醚的负离子受热,发生[2,3]单键转移(σ转移)反应,生成烯丙基芳甲基醇化合物。类似的含硫、含氮的化合物也有同样的重排反应。

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