1) H2 elimination
脱H2反应
1.
The isomerization reaction of CH3S→CH2SH (R1), H2 elimination reaction of CH3S→HCS+H2 (R2) and the isomerization reaction of HCS→CSH (R3) have been studied by using the density functional theory.
采用密度泛函方法(MPW1PW91)在6-311G(d,p)基组水平上研究了CH3S自由基H迁移反应CH3S→CH2SH(R1),脱H2反应CH3S→HCS+H2(R2)以及脱H2产物HCS异构化反应HCS→CSH(R3)的微观动力学机理。
2) vice reaction of H_2
析H2副反应
1.
The recoverits of gold electrowinning from dilute cyanide solutions is about 98% by means of using porous electrode, lowering vice reaction of H_2 and two stage electrolysis.
用电极过程动力学对从氰化贵液中直接电沉积金过程进行分析,可得出提高Au(CN)2-离子与阴极碰撞几率和减小析H2副反应是提高电沉积金效率的关键因素。
3) deoxygenation
脱氧反应
1.
Deoxygenation in the synthesis of taxol
紫杉醇合成中的脱氧反应
2.
A New Approach to Selective Deoxygenation of Bile Acids;
胆汁酸选择脱氧的新方法李开喜,徐正邦,余锐,赵华明(四川大学化学系,成都610064)关键词胆汁酸;冠醚;钾;脱氧反应;自由基醇的自由基脱氧方法在天然产物的合成中受到普遍的重视[1]。
4) dehalogenation
脱卤反应
1.
For most reduction reactions concerned,dehalogenation occurred seriously in hydrogenation reaction.
结果显示,催化加氢工艺会发生脱卤反应,而采用铁粉还原的选择性好,产品纯度高。
2.
Studies on Catalytic Hydrogenating Dehalogenation of Benzene Halide;
采用可溶性有机高分子负载钯络合物作催化剂 ,在无机碱 (NaOH)存在下于 2 0~ 65℃的有机溶液中进行常压加氢脱卤反应。
5) dechlorination
脱氯反应
1.
The mechanism and kinetics of dechlorination were studied in order to reduce dechlorination.
研究发现碱性条件下D4(八甲基环四硅氧烷)与MCPS(γ-氯丙基甲基二甲氧基硅烷)直接共聚时,副反应脱氯反应是聚合反应强烈的竞争反应。
2.
At ambient temperature and pressure, the natural and the enhanced reductive dechlorination of 4-chlorophenol (4-CP) in soils with zero-valent iron (ZVI) were investigated in the laboratory with isothermal incubation and gas chromatography mass spectrometry (GC-MS) as the primary analytical method.
以恒温培养为方法,GC-MS为检测手段,研究了在常温常压下土壤中4-氯苯酚(4-CP)在零价铁作用下的还原脱氯反应。
3.
In this laboratory study,the effects of zero valent iron(ZVI),noble metals modified ZVI,and other reaction controlling factors on the reductive dechlorination of hexachloroethane(HCE) were investigated under conditions of isothermal incubation.
实验证明:Fe0及其负载Pd、Pt、Rh多组分金属体系对六氯乙烷都有还原脱氯作用,Pd、Pt、Rh之间不存在协同催化还原脱氯效应;反应初始pH呈酸性时有利于脱氯反应进行;加入甲醇能够提高六氯乙烷在土壤溶液中的溶解度,但不能有效提高其在土壤中的还原脱氯率;甲酸铵是Fe0体系对六氯乙烷还原脱氯的良好助剂,当甲酸铵加入量为400mg时,用Fe0还原六氯乙烷脱氯率可以提高59%左右;相同实验条件下,用Pd/Fe还原六氯乙烷的脱氯率可以提高77%左右。
6) dehydration
[英][,di:hai'dreiʃən] [美][,dihaɪ'dreʃən]
脱水反应
1.
The Chemistry of α-Oxo Ketene Cyclic Dithioacetals(Ⅳ)——Studies on the Dehydration of Adducts of β,β-1,3-Propylene-dithio-α,β-Unsaturated Arylketones with Allyl Grignard Reagents;
α-羰基烯酮环二硫代缩醛化学(Ⅵ)——β,β-1,3-亚丙二硫基-α,β-不饱和芳酮与烯丙基Grignard试剂加成物脱水反应的研究
2.
The dehydration kinetic equation and the kinetic parameters of [Sm(m-BrBA)3phen]2·2H2O were studied by DSC techniques.
用差示扫描量热(DSC)技术研究了该配合物脱水反应的动力学方程和动力学参数。
3.
The kinetics of dehydration of β-cyclodextrin, inclusion compound of β-cyclodextrin with 4-(4-nitrophenylazo)-1-naphthol was studied under non-isothermal condition with TG, DTG.
用非等温热重法研究 β-环糊精、β-环糊精· 4 -( 4 -硝基苯偶氮 ) -1 -萘酚包合物的脱水反应动力学 。
补充资料:脱甲酰基反应
分子式:
CAS号:
性质:从有机化合物分子中脱掉甲酰基(-CHO)的反应。脂肪族醛和芳香醛在三(三苯基膦)合氯化铑或钯-碳等催化剂作用下,可以脱掉甲酰基生成相应的烃。脱甲酰基反应属于脱羰基反应(decarbonylation)范围,是最重要的脱羰基反应。
CAS号:
性质:从有机化合物分子中脱掉甲酰基(-CHO)的反应。脂肪族醛和芳香醛在三(三苯基膦)合氯化铑或钯-碳等催化剂作用下,可以脱掉甲酰基生成相应的烃。脱甲酰基反应属于脱羰基反应(decarbonylation)范围,是最重要的脱羰基反应。
说明:补充资料仅用于学习参考,请勿用于其它任何用途。
参考词条