1)  allylic alcohol
烯丙基醇
1.
Trichloroisocyanuric acid-base can be used as an efficient oxidant for the epoxidaiton of enones and tandem oxidation-epoxidation of allylic alcohols in a water-suspension system as completely organic solvent free reactions.
在水悬浮体系中使用三氯异氰尿酸/碱氧化体系对α,β-不饱和酮化合物进行环氧化和对烯丙基醇类化合物进行直接氧化-环氧化制备α,β-环氧酮,考察了表面活性剂、碱等因素对反应的影响。
2)  homoallyl alcohol
高烯丙基醇
1.
Allylsamarium bromide, prepared by the reaction of allyl bromide with samarium in THF at room temperature, reacted via 1,2-addition with α,β-unsaturated aldehydes or ketones to give homoallyl alcohol.
烯丙基溴与金属钐在室温条件下、THF溶剂中反应生成中间体烯丙基溴化钐 ,烯丙基溴化钐再与α ,β 不饱和醛、酮反应生成高烯丙基醇 。
3)  homoallylic alcohol
高烯丙基醇
1.
Allylation of terminal epoxides 1 can be carried out successfully by allyl bromide and metallic zinc or tin in a novel one-pot synthesis to give the homoallylic alcohols 2 and bishomoallylic alcohols 3.
烯丙基溴和金属锌或锡可成功地将末端环氧化合物1-锅法合成高烯丙基醇2和双高烯丙基醇3。
2.
Easy access to synthesize branched homoallylic alcohols was investigated.
通过铟促进下醛与2-苯基-4-溴-2-丁烯在水相中经烯丙基化反应合成一系列的支链高烯丙基醇,产率较高,反应条件温和。
3.
The enantioselective allylation of carbonyl compouds is one of the most valuable methods to furnish chiral homoallylic alcohols, which are widely used in the syntheses of many natural products and biologically active compounds.
高烯丙基醇广泛应用于许多天然产物和具有生物活性化合物的合成。
4)  α-methylhomoallylic alcohols
α-甲基烯丙基醇
1.
α methylhomoallylic alcohols are important intermediates used for synthesizing some macrolides and polyether antibiotics.
α－甲基烯丙基醇是合成一些大环内酯（ｍａｃｒｏｌｉｄｅ），聚醚抗生素（ｐｏｌｙｅｔｈｅｒａｎｔｉｂｉｏｔｉｃｓ）和信息素的重要中间体［１］。
5)  bishomoallylic alcohol
高高烯丙基醇
6)  linear homoallylic alcohol
直链高烯丙基醇
1.
The results showed that aliphatic aldehydes led to the linear homoallylic alcohols in moderate yields with excellent se-lectivities with indium triflate as catalyst in toluene.
结果发现,在In(OTf)3催化下,以甲苯为溶剂,由脂肪族醛合成的直链高烯丙基醇较芳香族醛具有较高的产率和较好的选择性,所得产物结构经1H NMR,13C NMR,IR,HRMS表征。
参考词条
补充资料：2-甲基烯丙基醇
分子式：C4H8O
分子量：72.1066
CAS号：513-42-8

性质：暂无

制备方法：暂无

用途：该产品是一种重要的有机中间体。用于合成香料、树脂等。

说明：补充资料仅用于学习参考，请勿用于其它任何用途。