1) Heterotrinuclear complex
异三核配核合物
2) heterotrinuclear complex
异三核配合物
1.
Oxamidato-bridged heterotrinuclear complex [Zn(CuL)_2N_3]-(ClO_4)·1.
合成了一个草酰胺桥联的异三核配合物,并解析了配合物的晶体结构,配合物处于正交晶系,空间群为Pbcn,a=1。
2.
Seven novel oxalate bridged heterotrinuclear complexes with general formula [M 2Fe (C 2O 4) 3L x ](ClO 4)(M=Cu,L=bpy,Me 2phen,NO 2phen, x =2; M=Ni,Co,L=bpy,Me 2phen, x =4) have been synthesized and characterized by elemental analysis, IR, electronic spectra, molar conductance and magnetic moments (at room temperature) measurements.
合成了 7种草酸根桥联的 Cu 2 Fe 、Ni 2 Fe 、Co 2 Fe 异三核配合物 [M2 Fe(C2 O4) 3Lx](Cl O4) ,(M=Cu,L=bpy,Me2 phen,NO2 phen,x=2 ;M=Ni,Co,L=bpy,Me2 phen,x=4 ) 。
3) heterotrinuclear complexes
异三核配合物
1.
Synthesis and magnetic properties of Cu(Ⅱ)-Mn(Ⅱ)-Cu(Ⅱ) heterotrinuclear complexes;
Cu(Ⅱ)-Mn(Ⅱ)-Cu(Ⅱ)异三核配合物的合成与磁性研究
2.
Six novel heterotrinuclear complexes of Ni(Ⅱ) Cu(Ⅱ) Ni(Ⅱ) have been synthesized, { 2}(ClO 4) 2·H 2O and { 2[Cu(Meopba)]}(ClO 4) 2·H 2O.
合成了 6种Ni(Ⅱ ) -Cu(Ⅱ ) -Ni(Ⅱ )的异三核配合物 { [(L) 2 Ni]2 [Cu(opba) ]} (ClO4) 2 ·H2 O ,{ [(L) 2 Ni]2 [Cu(Meopba) ]} (ClO4) 2 ·H2 O [opba =N ,N/-o -phenylenebis(oxamato) ,Meopba =4 -methyl-N ,N/- 1,2 -phenylenebis -(oxamato) ,L =2 ,2′ -bipyridyl(bpy) ,1,10 -phenanthroline(phen)和 4 ,4 -dimethyl- 2 ,2′ -bipyridyl(Mebpy) ]。
3.
Four new heterotrinuclear complexes through oxalato bridge have been synthesized, namely [Cu 2Fe(C 2O 4) 3L 2](NO 3)(L=phen, Mephen, Me 2phen, NO 2phen).
合成了四种新的草酸根桥联的异三核配合物 [Cu2 Fe(C2 O4 ) 3L2 ](NO3) (L=phen,Mephen,Me2 phen,NO2 phen)。
5) trinuclear complex
三核配合物
1.
An asymmetrical double Schiff base Cu(Ⅱ) mononuclear complex HCuLe(Where H_(3)Le is N-3-carboxylsalicylidene-N′-(5-chlorosalicylaldehyde-1,2-diaminoethane)) and its trinuclear complexes Cu(Ⅱ)M(Ⅱ)Cu(Ⅱ)(M=Co,Cu) were synthesized and characterized by means of elemental analysis,IR and(electron) spectrometries.
合成了不对称双Schiff碱Cu(Ⅱ)单核配合物HCuLe(H3Le为N-3-羧基水杨醛-N-(′5-氯水杨醛)缩乙二胺)及三核配合物Cu(Ⅱ)Co(Ⅱ)Cu(Ⅱ)和Cu(Ⅱ)Cu(Ⅱ)Cu(Ⅱ),用元素分析、红外光谱、电子光谱测试技术对它们进行了表征。
2.
Four trinuclear complexes have been prepared,[Cu_3(phth)_2(phen)_3](ClO_4)_2(1),[Cu_3(phth)_2(NO_2-phen)_3](ClO_4)_2(2),[Ni_3(phth)_2(phen)_3](ClO_4)_2(3)and[Ni_3(phth)_2(NO_2-phen)_3](ClO_4)_2(4)(phth=phthalato,phen=1,10-phenanthroline,NO_2-phen=5-nitro-1.
本文合成了4个三核配合物:[Cu_3(phth)_2(phen)_3](ClO_4)_2(1),[Cu_3(phth)_2(NO_2-phen)_3](ClO_4)_2(2),[Ni_3(phth)_2(phen)_3](ClO_4)_3(3)和[Ni_3(phth)_2(NO_2-phen)_3](ClO_4)_2(4)(phth=邻苯二甲酸根,phen=1,10-菲咯啉。
3.
By using a macrocyclic oxamide-Cu(Ⅱ)complex ligand as precursor,a novel trinuclear complex(CuL)_2(C_2H_5OH)_2](ClO_4)_3 has been prepared and characterized by X-ray diffraction analysis.
以一个草酰胺大环铜配合物为前驱体,设计合成了一个新颖的三核配合物,并对其进行了元素分析、红外光谱,电子顺磁共振以及 X 射线单晶衍射等表征。
6) oxo_centered heterotrinuclear complex
异三核氧中心配合物
1.
A new oxo_centered heterotrinuclear complex [Cr 2MnO(phCO 2) 6 py 3] +·CrO 3Cl - was synthesized, and characterized by elemental analysis and IR.
合成了一种新型异三核氧中心配合物 ,得到该配合物单晶 ,用元素分析、红外光谱进行了表征 ,研究了配合物的磁性质 。
补充资料：核火箭
利用核火箭发动机推进的火箭（见核火箭发动机）。
说明：补充资料仅用于学习参考，请勿用于其它任何用途。
参考词条