1) sulfate ester
硫酸酯基
3) glycosyl isothiocyanate
糖基异硫氰酸酯
1.
Fifteen target compounds were synthesized with the following three steps: amino acids were protected to form carbobenzoxyamino acid methyl esters, the carbobenzoxyamino acid methyl esters reacted with hydrazine to give carbobenzoxy amino acid hydrazides, and treatment of the carbobenzoxy amino acid hydrazides with glycosyl isothiocyanates afforded 3a~3o in 65%~86% yields.
通过对5种氨基酸酯化和氨基保护得到苄氧羰基氨基酸甲酯,经肼解制备苄氧羰基氨基酸酰肼,然后分别与3种不同的糖基异硫氰酸酯反应,制备了相应的目标化合物15个,且产率均在60%以上。
2.
The reaction of 2 with glycosyl isothiocyanates 3~5 gave the novel compounds, N-glycosyl-N'-amido thioureas 6~8.
以L-α-氨基酸为起始原料,经酯化、氨基保护、肼解制得N-对甲苯磺酰基-L-α-氨基酸酰肼2,再与糖基异硫氰酸酯3~5反应,得到9种新型N-糖基-N'-酰氨基硫脲6~8,然后在Hg(OAc)2/EtOH条件下关环,合成了一系列新的2-对甲苯磺酰氨基烃基-5-糖氨基-1,3,4-噁二唑类化合物9~11。
3.
The glycosyl isothiocyanates 1a~1c reacted with anhydrous hydrazine gave N-glycosyl- N'-aminothioureas 2a~2c, which then reacted further with 6-substituted-3-formylchromones 3a~3d to give a series of new N-glycosyl-N′-6-substitutedchromon-3-ylmethylideneaminothioureas 4a~4d, 5a~5d, 6a~ 6d.
糖基异硫氰酸酯(1a~1c)与无水肼反应,生成糖基氨基硫脲2a~2c,再与6-取代-3-甲酰基色酮3a~3d反应,得到一系列新的N-糖基-N′-(6-取代色酮-3-基-亚甲氨基)硫脲类化合物4a~4d,5a~5d,6a~6d。
4) Alkyl sulfatases
烷基硫酸酯酶
1.
Alkyl sulfatases can do it during catalysis by inversion or retention of substrate's configuration.
在工业生物技术中,大多数催化生产非天然化合物的水解酶对于对映异构体都有一定的偏爱性,如羧酸酯水解酶、脂肪酶以及蛋白酶,但它们在催化过程中不能改变底物的立体化学结构,而烷基硫酸酯酶可以通过倒置或保留底物构型来改变底物的立体化学。
5) thiocarbamate
[,θaiəu'kɑ:bəmeit]
硫代氨基甲酸酯
1.
A Method to Compound the Intermediate of Thiocarbamate;
硫代氨基甲酸酯中间体的合成
2.
Synthesis of Thiocarbamates via Selenium-mediated Carbonylation of Aniline with Thiols;
硒作用下苯胺和硫醇羰基化合成硫代氨基甲酸酯
3.
Determination of Seven Thiocarbamate Herbicides in Black Tea and Green Tea by Liquid Chromatography Coupled with Tandem Mass Spectrometry Detection
液相色谱-串联质谱法同时测定红茶和绿茶中7种硫代氨基甲酸酯类除草剂
6) sulfated polysaccharide
硫酸酯基多糖
1.
Chemical analysis of the sulfated polysaccharides extracted in different ways from the Eucheuma gelatinae and Eucheuma striatum;
琼枝和异枝麒麟菜中硫酸酯基多糖不同提取方法的化学分析比较
补充资料:2-[2-(3-氨基苯甲酰胺基)乙基砜基]乙醇硫酸酯
分子式:C11H16N3O7S2
分子量:暂无
CAS号:121315-20-6
性质:暂无
制备方法:暂无
用途:暂无
分子量:暂无
CAS号:121315-20-6
性质:暂无
制备方法:暂无
用途:暂无
说明:补充资料仅用于学习参考,请勿用于其它任何用途。
参考词条