1) copper(I) arylacetylides
苯乙炔化亚铜
1.
Arylbenzo[b]furans were obtained via coupling reaction of the copper(I) arylacetylides with the phenylbromide, and then a series of derivatives were designed and synthesized by reduction, Vilsmeier, hydrolysis and substituted reaction.
以4-取代苯乙炔化亚铜与3-甲氧基-4-羟基-5-溴肉桂酸甲酯为原料进行缩合反应得到2-取代芳基并[b]呋喃,并将其衍生化,得到14个2-芳基-5-烷基-7-甲氧基苯并[b]呋喃化合物,并确证了其结构。
2) cuprous acetylide
乙炔化亚铜
4) copper acetylide
乙炔单亚铜
5) mercurous acetylide
乙炔化亚汞
6) Poly(arylene ethynylene)
聚对亚苯基乙炔
1.
Poly(arylene ethynylene)s,P1 and P2 containing 1,3,5-triazine and chalcone unites respectively,were synthesized by Sonogashira coupling reaction.
本工作分别将1,3,5-三嗪环和查尔酮两类结构单元通过Sonogashira偶联反应引入聚对亚苯基乙炔的主链中,合成两类新型共轭聚合物,并对它们的荧光特性进行了比较。
补充资料:乙炔化
乙炔化
Ethynylation
ylqUeEthynylation见乞炔。化hua炔乙
说明:补充资料仅用于学习参考,请勿用于其它任何用途。
参考词条