1) aryl acetic acids
芳基乙酸
1.
Eight of corresponding aryl acetic acids were synthesized from series substitutional acetophenone through Willgerodt-Kindler reset and hydrolysis reaction.
以各种芳基乙酮为原料,通过Willgerodt-Kindler重排反应、水解反应合成了8个相应的芳基乙酸类化合物。
2) aryloxy acetic acid
芳氧基乙酸
1.
The reaction of aryloxy acetic acid with thiosemicarbazide in the presence of dehydrating agent,POCl_3,affords a series of 2amino5aryloxymethyl1,3,4thiadiazoles under microwave irradiation (MWI).
在三氯氧磷作用下,由芳氧基乙酸和氨基硫脲经脱水环合,微波辐射快速合成了一系列2氨基5芳氧亚甲基1,3,4噻二唑类化合物。
3) ethyl arylglyoxylate
芳基乙酮酸乙酯
1.
By the Friedel-Crafts acylation reaction with aromatic compounds 1a～1h and ethyl oxalyl chlo-ride as the starting materials,eight ethyl arylglyoxylates 2a～2h have been synthesized,and their structures were confirmed by IR,1H NMR spectra and elemental analyses.
以芳烃和草酰氯单乙酯为原料,采用Friedel-Crafts酰基化反应合成了8种芳基乙酮酸乙酯,用IR,1H NMR,元素分析确认了合成化合物结构,并用高效液相色谱法分析了反应的选择性。
4) asymmetric inductions
α-羟基芳基乙酸
5) arylsulfonylacetate
芳磺酰基乙酸酯
1.
The effects of substistution groups at the phenyl ring of reactant-arylsulfonylacetates on the addition-rearrangement reaction were examined.
研究了反应物-芳磺酰基乙酸酯苯环上取代基对加成-重排反应的影响,发现只有当芳环上4位或2位有硝基时,在K2CO3-TEBA相转移催化体系中,芳磺酰基乙酸酯与α,β-不饱和酯反应才可发生加成-重排反应,生成2-芳基戊二酸酯,其机理可能是芳磺酰基乙酸酯与α,β-不饱和酯首先发生Michael加成反应,随后加成产物发生分子内的亲核取代,酸化后脱去SO2得2-芳基戊二酸酯。
6) ethyl 3-arylpropionate
3-芳基丙酸乙酯
补充资料：芳基,芳基二乙基-芳基-甲基苯二胺
CAS：68479-98-1
分子式：C11H18N2
中文名称：二乙基甲苯二胺；芳基,芳基二乙基-芳基-甲基苯二胺
英文名称：ar,ar-diethyl-ar-methyl-Benzenediamine；Diethyltoluenediamine；ar,ar-diethyl-ar-methylbenzenediamine；ar,ar-diethyl-ar-methyl-benzenediamin；diethyl tolamine
分子式：C11H18N2
中文名称：二乙基甲苯二胺；芳基,芳基二乙基-芳基-甲基苯二胺
英文名称：ar,ar-diethyl-ar-methyl-Benzenediamine；Diethyltoluenediamine；ar,ar-diethyl-ar-methylbenzenediamine；ar,ar-diethyl-ar-methyl-benzenediamin；diethyl tolamine
说明：补充资料仅用于学习参考，请勿用于其它任何用途。
参考词条