1) Baylis-Hillman adduct
Baylis-Hillman加成物
1.
Five novel 4,4-dimethylisoxazolidin-3-one derivatives were designed and synthesized utilizing Baylis-Hillman adducts as starting materials.
以Baylis-Hillman加成物为起始原料,设计并合成了5个结构新颖的4,4-二甲基异唑-3-酮衍生物。
2) Baylis-Hillman reaction
Baylis-Hillman反应
1.
A C—C bond forming reaction, namely Baylis-Hillman reaction, is described and the recent progress is reviewed in the study of the reaction mechanisms of the single molecular aldehyde and the double molecular aldehyde, TiCl4 catalytic mechanism, asymmetric induction mechanism, temperature and solvent effects as well as the ionic liquid reaction mechanism.
介绍了一种形成碳—碳键的方法——Baylis-Hillman反应,综述了单分子醛、双分子醛反应机理、TiCl4催化机理、不对称诱导机理以及低温效应、溶剂效应、离子液体反应机理的研究进展。
2.
Baylis-Hillman reaction, which has great practical prospect, can be catalyzed by amine or phosphine.
Baylis-Hillman反应是一类非常有应用前景的有机合成反应,常用的催化剂包括胺类、有机膦等。
3.
The Baylis-Hillman reaction, a carbon-carbon bond forming reaction, is one of the very few re-actions wherein atom economy is perfectly preserved.
Baylis-Hillman反应是一个为数不多的形成碳—碳键的原子经济反应,因其产物富含官能团而成为非常有潜力的合成有机多功能分子的有力工具。
3) Baylis-Hillman reaction
Baylis-Hillman 反应
1.
Synthesis and application of Chiral Organocatalysts in the Asymmetric Baylis-Hillman Reaction Chiral catalysts 1-4 were prepared conveniently from amino acids, and applied in asymmetric Baylis-Hillman reaction to study the relationship between catalyst structure and enantioselectivity.
手性有机小分子催化剂的合成及催化Baylis-Hillman 反应研究以易得的氨基酸为原料,合成了催化剂1、2、3 和4,并用于催化Baylis-Hillman反应。
4) Morita-Baylis-Hillman Reactions
Morita-Baylis-Hillman反应
1.
Study on the Asymmetric Catalysis Morita-Baylis-Hillman Reactions;
催化不对称Morita-Baylis-Hillman反应的研究
补充资料:加成物
分子式:
分子量:
CAS号:
性质:由加成反应生成的产物。例如氯乙烯 CH2=CHCl 是乙炔 CH≡CH 和氯化氢HCl的加成物,光气COCl2是一氧化碳CO和氯Cl2的加成物。
分子量:
CAS号:
性质:由加成反应生成的产物。例如氯乙烯 CH2=CHCl 是乙炔 CH≡CH 和氯化氢HCl的加成物,光气COCl2是一氧化碳CO和氯Cl2的加成物。
说明:补充资料仅用于学习参考,请勿用于其它任何用途。
参考词条