1) Atom transfer radical polymerization
原子转移自由基聚合反应
1.
Atom transfer radical polymerization(ATRP) has been widely used as an effective method for living polymerization of various kinds of monomers.
活性聚合反应是目前高分子合成研究最为活跃的领域之一,原子转移自由基聚合反应(ATRP)是实现活性聚合的一种有效途径,可实现多种单体的活性聚合和可控自由基聚合。
2) chain-transfer radical polyperization
自由基链转移聚合反应
3) atom transfer radical polymerization
原子转移自由基聚合
1.
Progress in catalyst system of atom transfer radical polymerization;
原子转移自由基聚合催化体系的研究进展
2.
Synthesis of 4-arm methyl methacrylate star polymer by atom transfer radical polymerization;
原子转移自由基聚合制备四臂聚甲基丙烯酸甲酯星形聚合物
3.
Synthesis of polylactide block copolymer by atom transfer radical polymerization;
原子转移自由基聚合法制备聚乳酸三嵌段共聚物的研究
4) atom transfer radical polymerization(ATRP)
原子转移自由基聚合
1.
Polystyrenes with 1,1-diphenylethene(DPE) pendent groups were synthesized via atom transfer radical polymerization(ATRP).
通过原子转移自由基聚合(ATRP)制备了含1,1-二苯基乙烯(DPE)侧基的聚苯乙烯。
2.
The POSS/PMMA core-shell nanocomposite particles were prepared by atom transfer radical polymerization(ATRP) in the presence of CuCl/2,2'-bipyridine as the catalyst and the monofunctional group POSS-Cl as the initiator.
文章以CuCl/2,2’-联吡啶为催化剂,单功能基POSS-Cl为引发剂,采用原子转移自由基聚合方法制备了POSS/PMMA核壳型结构的纳米复合材料,通过FTIR1、H-NMR、XPS等手段对其进行表征,并用DSC、TGA等检测手段对其热性能进行研究。
3.
A pH-sensitive chitosan material was prepared via atom transfer radical polymerization(ATRP) of chitosan with poly(ethylene glycol) methacrylate(PEGMA),which was successfully conducted in water and methanol system with CS-Br as macroinitiator and CuBr/bpy as a catalyst.
合成了大分子引发剂壳聚糖(CS)接枝α-溴代异丁酰溴(CS-Br),然后利用原子转移自由基聚合(ATRP)合成了一种新型pH敏感性的壳聚糖材料———壳聚糖接枝α-溴代异丁酰溴共聚甲基丙烯酸聚乙二醇酯P(CS-Br-PEGMA),并对其结构进行了表征,研究了其对辅酶A(CoA)的控制释放,结果发现在24℃、P(CS-Br-PEGMA)在不同浓度或pH在3。
5) atom transfer radical polymerization(ATRP)
原子转移自由基聚合(ATRP)
1.
A star poly(N-isopropylacrylamide) withα-D-glucose-based group was synthesized via Atom Transfer Radical Polymerization(ATRP) in this dissertation.
带有生物活性官能团聚合物具有很好的生物兼容性,本论文采用原子转移自由基聚合(ATRP)的方法合成了一种以α-D-葡萄糖为核的星形聚N-异丙基丙烯酰胺,对聚合过程的动力学及聚合物的热敏性进行了研究。
2.
Atom transfer radical polymerization(ATRP) was applied to prepare an amphiphilic azobenzene-containing ABA triblock copolymer PMAA-b-PMAZOCNb-PMAA.
利用原子转移自由基聚合(ATRP)制备了中间链段含对氰基偶氮苯尾挂液晶基元的PMAA-b-PMAZOCN-b-PMAA两亲性三嵌段共聚物。
6) ATRP
原子转移自由基聚合
1.
STUDY ON ATRP Of MMA INITIATED BY CHOLESTERYL CHLOROFORMATE;
氯甲酸胆固醇酯引发的MMA原子转移自由基聚合反应
2.
Synthesis of the Graft Copolymer of Poly (styrene g butylacrylate) by ATRP;
原子转移自由基聚合合成聚(苯乙烯-g-丙烯酸丁酯)
3.
A novel well-defined amphiphilic copolymer was prepared via atom transfer radical polymerization(ATRP) with 2-bromoisobutyrate-capped poly(9,9-dihexylfluorene) as macroinitiator and CuCl/HMTETA(1,1,4,7,10,10-hexamethyltriethylenetetramine) as the catalyst.
以两端溴化的聚9,9-二己基芴作为大分子引发剂,6-O-甲基丙烯酰基-1,2:3,4-二-O-异亚丙基-D-吡喃型半乳糖(6-O-Methacryloyl-1,2:3,4-di-O-isopropylidene-D-galactopyranose,MaIpGa)为单体,氯化亚铜/1,1,4,7,10,10-六甲基三乙基四胺为催化剂,通过原子转移自由基聚合(ATRP),合成了一种新型的具有良好光学性能的三嵌段共聚物聚甲基丙烯酸羟基保护半乳糖酯-聚芴-聚甲基丙烯酸羟基保护半乳糖酯(PMaIpGa-PF-PMaIpGa)。
补充资料：游离基连锁聚合反应(radicalchainpolymerization)
【游离基连锁聚合反应】(radicalchainpolymerization)亦称“游离基聚合”。洗化中心为游离基的连锁聚合反应。反应温度一般为50-100℃。进行聚合反应的单体多数是具有吸电子取代基的`\alpha`烯烃和共轭二烯烃，如苯乙烯、氯乙烯、甲基丙烯酸甲酯、丙烯腈和丁二烯等。在工业化生产的高聚物中，大多数产品由此反应制得。
说明：补充资料仅用于学习参考，请勿用于其它任何用途。
参考词条