1) oxime ethers containing indanone
茚酮肟醚
1.
Ten oxime ethers containing indanone were synthesized by Friedel-Crafts reaction,cyclization,oximation,etherification.
通过傅-克反应及环化、肟化、成醚等反应,合成了10个未见文献报道的茚酮肟醚类化合物,其结构均经1H NMR、IR、LC/M S及元素分析确证。
2) 2-Indanone oxime
2-茚酮肟
3) ketoxime ethers
酮肟醚
1.
These reagents were used in asymmetric reduction of C = N double bonds of aliphatic and aromatic ketoxime ethers to yield chiral primary amines, which are (S) - configuration in most of the cases, with chemical yields(52-76% ) and optical yields(6-99% ).
光学活性(S)-(-)-2-(1-吡咯烷基)-1,1-二苯基-丙醇-1(1a)和(S)-(-)-2(1-吡咯烷基)-1,1,3-三苯基-丙醇-1(1b),分别与过量的硼烷反应,生成相应的硼烷-手性鎓唑硼烷配合物,可用于脂肪酮肟醚和芳香酮肟醚的碳-氮双键的不对称还原反应,得到光学活性伯胺,化学收率则为52～76％,光学收率为6～99％,讨论了不同还原底物的结构对立体选择性的影响作用。
4) ketone oxime O-ether
酮肟-O-醚
5) oxime ether
肟醚
1.
Synthesis and Activity of Novel Oxime ether-acylamides;
肟醚-酰胺衍生物的合成与生物活性研究
2.
Synthesis of novel indene-substituted oxime ether compounds;
结构新颖的茚取代肟醚类化合物的合成
3.
In search of novel pesticide leading compound with high bioactivity,thirty-five 4-chloro-phenyl methyl ketone oxime ether derivatives were designed and synthesized by the reaction of 2-substituted amino 4-chlorophenyl methyl ketone oxime with halohydrocarbon.
为寻找高活性的新农药化合物,通过2-取代氨基-1-对氯苯乙酮-1-肟与卤代烃反应,设计并合成了35个对氯苯乙酮肟醚衍生物,其结构均经核磁共振氢谱和元素分析确证。
6) oxime-ether
肟醚
1.
Aimed to find new pesticide with high activity and low toxicity, nine novel benzoyl ureas containing oxime-ether group were synthesized according to bioisoster principle.
为寻找高效、低毒的新农药,依据活性基团拼接原理,合成了9个具有肟醚结构的苯甲酰脲类化合物。
2.
Aim To study the synthetic method and antibacterial activity of amino-heterocyclic compounds coupled oxime-ether group.
方法用4-氨基-3-甲基-5-巯基-[1,2,4]三唑与β-氯苯丙酮缩合、肟化、醚化得3-(4-氨基-5-甲基-均三唑-3-硫基)-1-苯丙-1-酮-O-(5-取代苯基-[1,3,4]噁二唑-2-甲基)肟醚目标化合物。
补充资料：2-茚酮
分子式 C9H8O
分子量 132.16
CAS号 615-13-4
2-茚酮为白色结晶。熔点56-58℃,闪点100℃。不溶于水。
用途;2-茚酮主要用于制备阿普林定（Aprindine）和头孢雷特（Ceforanide）等。
分子量 132.16
CAS号 615-13-4
2-茚酮为白色结晶。熔点56-58℃,闪点100℃。不溶于水。
用途;2-茚酮主要用于制备阿普林定（Aprindine）和头孢雷特（Ceforanide）等。
说明：补充资料仅用于学习参考，请勿用于其它任何用途。
参考词条