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1)  prolinol
脯氨醇
1.
Using inexpensive,convenient obtained NaBH_4-I_2-THF system,N-Cbz or Boc protected prolines were reduced into corresponding prolinols in mild condition with high chemical selectivity and good to high yields,and the protecting groups were not influenced.
采用价廉易得的NaBH_4-I_2-THF体系还原N-Cbz或Boc保护的脯氨酸,可以得到相应的脯氨醇,反应条件温和,产率高,化学选择性好,保护基不受影响。
2)  L-prolinol
L-脯氨醇
1.
Under the above mentioned conditions, the yield of L-prolinol could be reached 90 and the optical purity of L-prolinol was up to 97,α_D=+30.
用Zn(BH4)2还原L-脯氨酸制备了L-脯氨醇
2.
A new chiral auxiliary,non-cross-linked polystyrene(NCPS) supported L-prolinol was synthesized using L-prolinol as initiating material by four steps contained amino protected,etherification,polymerization,deprodection of amino group,and the overall yield was 50.
以L-脯氨醇为原料,经过氨基保护、成醚、聚合、脱叔丁氧羰基(Boc)4步反应合成了一种新的手性助剂——线型聚苯乙烯支载脯氨醇,总产率为50。
3)  Hydroxyprolinol
羟脯氨醇
4)  (R)-(-)-2-Hydroxymethylpyrrolidine
D-脯氨醇
5)  S-Proline derivatives
(S)-脯氨醇衍生物
6)  prolinol derivatives
脯氨醇衍生物
补充资料:L-脯氨醇
分子式:C5H11NO
分子量:101.15
CAS号:23356-96-9

性质:暂无

制备方法:暂无

用途:暂无

说明:补充资料仅用于学习参考,请勿用于其它任何用途。
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