1) N-H insertion
N-H插入反应
1.
The intermolecular N-H insertion reaction of methyl α-diazo phenylacetate with acetamide has been investigated by catalysis of transition metal complexes and under varying solvent.
研究了过渡金属配合物催化剂作用下,不同溶剂中-α重氮苯乙酸甲酯与乙酰胺的分子间N-H插入反应。
2) O-H insertion reaction
O-H插入反应
1.
In addition, the O-H insertion reaction of the α-diazo carbonyl compounds has been exploited.
本论文探讨了α-卤代-α,β-不饱和酯的新合成方法以及α-重氮羰基化合物的合成与O-H插入反应。
2.
Ethyl diazoacetate (EDA) undergoes a facile bis (salicylaldehydato) copper (Ⅱ) carbenoid mediated O-H insertion reaction with ethyl lactate to afford the title compound.
重氮乙酸乙酯(EDA)与乳酸乙酯在二水杨醛铜(Ⅱ)催化下进行O-H插入反应合成了α-甲基-缩二乙醇酸二乙酯。
3) C-H bond insertion realtion
C-H键插入反应
4) C-H insertion
C-H插入反应
5) O-H and S-H insertions
插入O-H和S-H键反应
6) Insertion reaction
插入反应
1.
The insertion reaction mechanism of CCl2 into CH2O has been studied by using the B3LYP/6-311G* and CCSD(T)/6-311G* at single-point.
采用密度泛函B3LYP/6-311G*和高级电子相关耦合簇[CCSD(T)/6-311G*]方法计算研究了CCl2与CH2O的插入反应机理,全参数优化了反应势能面各驻点的几何构型,用内禀反应坐标(IRC)和频率分析方法,对过渡态进行了验证。
2.
The paper studied catalyzed insertion reaction of α-diazo-β-dicarbonyl compounds into methanol and also investigated influence factors on the reaction, for example structures of diazo and alcohols, catalyst, solvent and reaction temperature.
研究了在过渡金属配合物催化下α-重氮-β-二羰基化合物与醇的插入反应,考察了重氮化合物的结构、醇的结构、催化剂的性质、反应溶剂和反应温度对这一反应的影响。
3.
The insertion reactions of CX 2 (X=H,F,Cl) with C-H bond in methyl isopropyl ether have been studied at MP2/6 31G(d) level by using ab initio molecular orbital theory.
用从头计算方法在MP2 /6 31G(d)水平上研究了CX2 (X =H ,F ,Cl)与甲基异丙基醚的C -H键插入反应。
补充资料：思维插入
思维插入
thought insertion
思维插入(th。ught Insertion)病人认为他的思想有些并不属于他自己，而是通过外力置入其脑内的。‘常伴有强制性思维(forced th一nking)体验，即病人感到思维不受他的意志支配，大量在脑内涌现，内容杂乱多变，巨出于他意料之外。此时，思维插入是病人对这种体验的妄想性解释。 (赵亚志撰刘协和审)
说明：补充资料仅用于学习参考，请勿用于其它任何用途。
参考词条