1) terminal alkyne
端基炔烃
1.
Then a highly efficient and stereoselective hydrosilylation of terminal alkynes was developed by using the Pt(DVDS)/proazaphosphatrane complex as catalyst.
含氮二环磷碱与Pt(DVDS)组成的催化体系,能高效高立体选择性地催化端基炔烃的硅氢加成反应,含氮二环磷碱及其改性的催化剂经31PNMR表征。
2) end groups
端基
1.
Theoretical design of high-spin biradical molecules with heterocycles as end groups;
以杂环做端基的高自旋双自由基分子的理论研究
3) end group
端基
1.
The results show that the dendrimers of ester as end group have visbreaking effect on the crude oil.
5代树状长链酯对原油的降黏性能,分析了树状大分子的端基结构对原油降黏性能的影响。
2.
Methoxy or methacrylic end groups were prepared,upon reacting the residual NCO moiety with either methanol or hydroxyethylmethacrylate.
NCO和OCH3为端基的PU构成的复合乳液GPC谱图都呈现两个峰,DSC和FT-IR分析发现,复合后增加了PU软段和硬段相分离的程度。
3.
Four open chain crown ethers using parahydroxylbenzaldehyde,β-aminoacid schiff base as end group were snythesized by the condensation of polyethylene glycol bridged diarylaldehyde with orthoaminobenzoic acid.
以多缩乙二醇桥连二芳醛与邻氨基苯甲酸的缩合合成了4种以对羟基苯甲醛、β—型氨基酸Schiff碱为端基的开链冠醚,并用IR、1HNMR和MS谱,确证了它们的结构。
4) Terminal group
端基
1.
Study on synthesis and properties or noncyclic crown ethers with phenyl thiocarbamide acetic acids as terminal groups;
以苯硫脲基乙酸为端基的开链冠醚的合成及其性质研究
2.
Three noncyclic crown ethers with 1 phenyl 3 benzoyl thiocarbamide as terminal groups were synthesized by treating diaromatic amides bridged in noncyclic crown ether with benzoyl isothiocyanate by refluxing acetone.
由苯甲酰基异硫氰酸酯、开链冠醚桥连二芳胺合成了3种以1-苯基-3-苯甲酰基硫脲为端基的开链冠醚,并用IR,1HNMR,MS等谱验证了其结构,初步试验了其与部分金属离子的络合性
5) end-group titration
端基滴定
1.
The determination of polymerization degree of ammonium polyphosphate by end-group titration;
端基滴定法测定聚磷酸铵聚合度
2.
Conclusion was made by comparing with the test result of nuclear magnetic resonance spectroscopy:the end-group titration is only suitable for testing average degree of polymerization of ammonium polyphosphate product with high water dissolvability and not suitable for produc.
根据端基滴定测试聚磷酸铵平均聚合度的方法,从交换过程、交换产物、滴定过程进行讨论,以及与核磁共振方法测定结果比较,认为聚磷酸铵平均聚合度的测试方法——端基滴定法只适宜测定水溶性的聚磷酸铵产品平均聚合度,对于水溶性差且平均聚合度大的聚磷酸铵产品用端基滴定法测定平均聚合度是不可行的。
6) end group
末端基
1.
Besides,the application of MALDI technique on the determination of molecular weight distribution,end group information,copolymer composition and mechanism of polymerization and degradation were reviewed.
并阐述了MALDI技术在确定聚合物相对分子质量分布,聚合物末端基团,共聚物组成和推断反应及降解机理上的应用。
参考词条
补充资料:炔烃
炔烃 alkyne 含碳-碳叁键的不饱和烃。通式CnH2n-2。最简单的炔烃是乙炔。 炔烃的系统命名法与烯烃相似,即选择含叁键的最长碳链为主链,从靠近叁键的一端开始编号,以侧链为取代基: HCCCH3 丙炔 CH3CCCH3 2-丁炔 3-甲基-1-丁炔 叁键在链端的直链炔烃的沸点和相对密度都比相应的烯烃和烷烃高,可能是由于分子间的吸引力较大。 炔烃中只有乙炔在工业上大量生产。乙炔的同系物可由乙炔化合物与卤代烷反应制得: CH3CH2CH2CH2Br+CH≡CNaCH3(CH2)3C≡CH+NaBr |
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