1) Nitrile
[英]['naitril] [美]['naɪtrəl]
腈
1.
A new method of synthesis for nitriles from N-metho xyimidoyl bromides by photolysis;
N-甲氧基偕溴代亚胺的光解成腈反应的研究
2.
Photolysis of (Z) N methoxyimidoyl bromides leads to formation of the corresponding nitriles in yields of 74%~87% without affecting other functional groups sensitive to ordinary dehydrating and halogenating reagents.
(Z)-N-甲氧基偕溴代亚胺化合物经光解制得相应的腈,收率达74% ~87% ,且羟基、羧基和酰胺基等不受影响。
3.
The intermolecular reductive cross-coupling of diaromatic ketones with nitriles induced by low-valent titanium reagent(TiCl4-Zn) affords ketones.
在低价钛(TiCl4-Zn)试剂作用下,腈与二芳酮发生分子间交叉还原偶联反应生成酮,而腈与1,3-二酮反应生成取代吡咯。
2) nitriles
腈
1.
this paper studied the intermolecular reductive coupling of nitriles with azides promo-ted by Sm/TMSCl/H2O (trace) system in aqueous media.
脒类化合物是重要的有机合成中间体,鉴于目前脒类化合物合成方法中的诸多不足,对Sm/TMSCI/H_2O(微量)体系促进的腈与叠氮化合物分子间的还原偶联反应进行了研究。
2.
Amine catalysts are used for preparation of thioamides by the addition reaction of nitriles with hydrogen sulfide.
在胺催化下,硫化氢和腈加成反应生成硫代酰胺,其原子经济性为100%,是一个绿色化学合成方法。
3) acetonitrile
[,æsitəu'naitril]
乙腈
1.
Development of a catalyst for selective hydrogenation of acetonitrile to ethylamine;
乙腈加氢制乙胺催化剂的研究
2.
Determination of concentration of lactic acid in fermented broth by gas chromatography with acetonitrile as internal standard;
利用乙腈作为内标气相色谱法快速测定发酵液中的乳酸
3.
Simulation and optimization of extractive butadiene with acetonitrileⅡ.Influence of mass fraction of acetonitrile,mass ratio of acetonitrile and C_4 feed and ratio of reflux on effect of separation;
乙腈法萃取精馏丁二烯过程模拟与工艺优化Ⅱ·乙腈质量分数、腈烃比和回流比对分离效果的影响
4) acrylic
[英][ə'krɪlɪk] [美][ə'krɪlɪk]
腈纶
1.
Study on thermodynamics of dyestuff adsorbed onto the acrylic surface using stoichiometric displacement theory;
计量置换理论用于染料在腈纶上吸附的热力学研究
2.
Anti-pilling research on physically modified acrylic fiber;
物理改性腈纶抗起毛起球性能研究
5) acrylic fiber
腈纶
1.
Analysis of causes influencing acrylic fiber solvent quality and countermeasures;
影响腈纶溶剂质量的原因分析及对策
6) recovered acrylonitrile water
腈水
1.
After the revamp,the acrylonitrile in recovered acrylonitrile water can be fully separated and recovered acrylonitrile concentration can exceed 90%,which prevents the polymerization resistant component in recovered acrylonitrile water from affecting polymerization reaction process,ensures polymerization reaction activity,stabilizes polymerization process,and improves the NBR quality.
改造后回收的丙烯腈水能够充分分离,得到浓度大于90%的丙烯腈,避免回收丙烯腈水中的阻聚成分对聚合反应工艺的影响,保证聚合反应活性,稳定聚合工艺,提高产品质量。
补充资料:腈
腈 nitrile 可以看作氢氰酸HCN的氢原子被烃基取代生成的化合物,通式R—C≡N。某些高级腈存在于植物精油中,例如,苯乙腈存在于独行菜、苦橙和铃兰花油中,苯丙腈存在于水田芥中,乙烯基乙腈也存在于多种植物中。最简单的腈是乙腈,它能与水互溶;丙腈在水中溶解度也很大;高级腈一般只微溶于水。低级腈多是无色液体,C14以上的腈则多是结晶形的固体。腈的沸点一般略高于相应的脂肪酸。腈有芳香气味。一般都很稳定。 腈可进行两大类反应:①在腈基上的反应,例如在酸或碱性溶液中水解成酰胺或羧酸,与格氏试剂加成、水解生成酮,还原成一级胺等。②α活泼氢的反应,例如在碱作用下进行烃基取代,或与羰基化合物缩合等。 腈主要由CN—与卤代烷反应或由酰胺脱水制得;芳香腈则可由重氮盐与氰化亚铜反应制得。腈是重要的化工原料和合成中间体。例如,己二腈是制备耐纶66的原料;丙烯腈则是生产聚丙烯腈的单体,它与其他单体共聚合可用于生产合成橡胶和工程塑料;乙腈是很好的有机溶剂;有些高级腈可用作香料。腈的毒性一般较氢氰酸低,有一些低级腈和不饱和腈毒性较大,如丙腈和乙腈的毒性与氢氰酸相近。多氰基化合物的毒性往往更大些。高级的腈一般是低毒或无毒的。 |
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