1) palladium acetate
乙酸钯
1.
Polyketone was prepared by the copolymerization of carbon monoxide and styrene catalyzed by polymer-based chelating nitrogen ligands resin-supported palladium acetate.
以负载有乙酸钯的功能化树脂微球组成的催化体系催化一氧化碳和苯乙烯共聚合成聚酮。
2.
Poly(1-oxo-2-phenyltrimethylene) (STCO)was synthesized by copolymerization of carbon monoxide and styrene in the presence of palladium acetate, neodymium acetate and copper/p-toluensulfonic acid.
利用乙酸钯、乙酸钕和对甲苯磺酸铜组成的催化体系催化一氧化碳和苯乙烯共聚,合成聚1-氧代-2-苯基丙撑(STCO)。
3.
Solvent stabilized Pd colloidal nanoparticles were prepared by a microwave thermal decomposition of palladium acetate in the environment of alkali and butyl alcohol .
首次报道了在丁醇及氢氧化钠条件下 ,采用微波热分解法加热分解乙酸钯制备了金属钯纳米颗粒 ,并用TEM、XPS对其进行了表征 。
2) palladium trifluoroacetate
三氟乙酸钯
3) Pd(Ph2PCH2COO)2
二苯基膦乙酸钯
1.
Six biaryl type liquid crystal compounds containing fluorine were synthesized by Suzuki coupling reaction between compound 5 and phenylboronic acid containing fluorine catalyzed by Pd(Ph2PCH2COO)2.
在二苯基膦乙酸钯催化下由化合物5与含氟苯硼酸偶联,合成了6个联苯类含氟液晶化合物。
4) palladium (II) trifluoroacetate
三氟乙酸钯(II)
5) palladium acetate
醋酸钯
1.
In this paper,a highly active catalyst system for synthesizing three novel secondary amines,such as N-phenyl-3,5-dimethylaniline,N-3,5-dimethylphenyl-4-methoxyaniline,N-3,5-dimethylphenyl-2-pyridylamine,was formed by combination of the chelating ligand bis[2-(diphenylphosphino]phenyl)ether(DPEphos) with palladium acetate.
以醋酸钯、膦配体二(2-二苯膦基)二苯醚(DPEphos)作为高活性催化系统,合成3个新的二级胺化合物N-苯基-3,5-二甲基苯胺、N-3,5-二甲苯对甲氧基苯胺和-N3,5-二甲苯基-2-吡啶胺。
6) Pd(OAc)2
醋酸钯
1.
The oxidation of cyclohexene to cyclohexanone catalyzed by Pd(OAc)2/HQ/FePcwas investigated in an acidic aqueous solution of acetonitrile.
在醋酸钯[Pd(OAc)_2]/氢醌(HQ)/酞菁铁(FePc)催化环己烯氧化合成环己酮反应中,应用XPS、UV-Vis、IR和循环伏安法考察了催化剂各组分在反应前后存在状态,以及Pd(OAc)2、Pd(OAc)2/BQ(苯醌)对环己烯的作用,FePc对HQ的催化氧化。
2.
In the presence of Pd(OAc)2(2 mol%),DABCO(4 mol%),CuI(2 mol%),NaOAc(3 mmol),MeCN(5 mL)and air,a variety of terminal alkynes(1 mmol)undergo homocoupling reaction smoothly to afford the corresponding diynes in moderate to excellent yields.
在醋酸钯(2 mol%)、碘化亚铜(2 mol%)、DABCO(4 mol%)、醋酸钠(3 mmol)、乙腈(5 mL)和空气氛等条件下,1 mmol的末端炔烃可以顺利发生自偶联反应生成相应的二炔化合物,产率为中等到良好。
补充资料:三氟乙酸钯(II)
分子式:Pd(CF3COO)2
CAS号:
性质:又称三氟醋酸钯(II)。棕色固体。熔点210℃(分解)。由硝酸钯(II)与三氟乙酸在硝酸存在下反应制得。用作偶联、脱氢反应的催化剂。
CAS号:
性质:又称三氟醋酸钯(II)。棕色固体。熔点210℃(分解)。由硝酸钯(II)与三氟乙酸在硝酸存在下反应制得。用作偶联、脱氢反应的催化剂。
说明:补充资料仅用于学习参考,请勿用于其它任何用途。
参考词条