1) Lactam
[英]['læktæm] [美]['læktæm]
内酰胺
1.
The Synthesis and the Technological Study of(2R,3S,4S)-3-(N,N-Diethylamino)-Formyloxy-4-Phenyl-5-Benzoyl-N-Methyl-Y-Lactam;
(2R,3S,4S)-2-(N,N-二乙氨基)甲酰氧基-3-苯基-4-苯甲酰基-N-甲基-Y-内酰胺的合成及工艺研究
2.
Chiral γ-lactam (pyrrolidinone) derivatives are a very important class of bioactive compounds that exist widely in the natural products, and they are versatile for the synthesis of drugs .
采用微波辐射和分子筛催化相结合的方法合成了高光学活性的γ- 内酰胺,并采用粗糙集理论进行了溶剂筛选。
3.
When hydrolyzed by peptidasesin vivo, this exotoxin releases tabtoxinine-β-lactam, which inhibits glutaminesynthetase, causing chlorosis and death of the tobacco plants[1].
Tabtoxinine-β-lactam 2具有内酰胺结构,是抗生素药物中常见的重要构效官能团 本文对Tabtoxinine-β-lactam 2的合成路线进行了新的改进与尝试。
2) Lactim-Lactam
内酰胺-内酰亚胺
3) β-lactam
β-内酰胺
1.
Synthesis and Stereochemistry of 3-(Thiophen-2-yl)-β-lactams;
3-(噻吩-2-基)-β-内酰胺的合成及其立体化学
2.
Effect of Microwave Irradiation on the Syn/Trans Selectivity in the Formation of β-Lactams From Ketenes and Imines;
微波对烯酮和亚胺形成β-内酰胺顺反选择性的影响
3.
Synthesis of α-Bromo-β-lactam Derivatives of 1,5-Benzothiazepines under Microwave Irradition;
微波作用下1,5-苯并硫氮杂-α-溴代-β-内酰胺衍生物的合成
4) caprolactam
[,kæprəu'læktəm]
己内酰胺
1.
Effect of ultraviolet on Phanerochaete chrysosporium for decomposing caprolactam and degrading polyamide 6;
紫外线照射白腐菌对己内酰胺分解及聚酰胺6降解的影响
2.
The research to the properties of soybean degradable material that modified by caprolactam;
己内酰胺改性对大豆分离蛋白可降解材料性能影响的研究
3.
Research on the Kinetics of Anionic Polymerization of Caprolactam to Nylon Using Adiabatic Method;
绝热法研究己内酰胺阴离子聚合尼龙动力学
5) ε-caprolactam
己内酰胺
1.
By means of anionic ring-opening copolymerization, a series of copolymers of ε-Capro-lactone with ε-caprolactam were synthesized at different lactam/lactone ratio, with the sodium hydroxide as catalyst, the aromatic diisocyanate as initiator, respectively.
以氢氧化钠为引发剂,芳香族二异氰酸酯为活化剂,用不同物质的量比的己内酰胺和己内酯,采用阴离子开环聚合工艺合成了一系列己内酰胺-己内酯共聚物。
2.
Recent development of vapor - phase Beckmann rearrangement of cyclohexanone oxime to ε-caprolactam catalyzed by molecular sieves was reviewed.
介绍了用以代替浓硫酸催化环己酮肟Beckmann重排反应制己内酰胺的各类分子筛催化剂的研究新进展,并 对其反应机理、催化剂的失活与再生、反应新工艺进行了阐述。
3.
The effects of preparation methods of TiO 2-ZrO 2 on catalytic performance of B 2O 3/TiO 2-ZrO 2 for vapor-phase Beckmann rearrangement of cyclohexanone oxime to ε-caprolactam were investigated.
考察了载体TiO2 ZrO2 的制备方法对B2 O3 /TiO2 ZrO2 催化环己酮肟气相Beckmann重排制己内酰胺反应性能的影响。
6) caprolactam
[,kæprəu'læktəm]
已内酰胺
1.
Aimed at the characteristics of complex ingredients, highly toxicity and hard to treat of production sewage of capro-lactam, the advanced technique of biological denitrification treatment of anaerobic/aerobic bacteria (A/O) has been used in the production sewage treatment of caprolactam and the technological design.
针对已内酰胺生产废水成分复杂、毒性大、难以处理的特点,应用先进的厌氧菌/好氧菌(A/O)生物脱氮技术对已内酰胺生产废水进行处理。
2.
The paper discussed the action mechanism and process of the advanced caprolactampolymerization production system in the world.
切片质量进一步提高,已内酰胺单耗下降了1。
3.
The production, supply and demand, and consumption of caprolactam in the world are outlined inthis paper, the severe situation which caprolactam industry recently faces is analyzed, and the suggestions for developing domestic caprolactam industry are also put forward.
概述了世界己内酰胺的生产、供需及消费情况;分析了目前已内酰胺工业所面临的严峻形势,并对我国已内酰胺工业的发展提出了建议。
补充资料:内酰胺
内酰胺 lactam 氨基酸分子内的氨基和羧基间失去一分子水而生成的环状化合物。γ或δ-氨基酸易失水形成γ或δ-内酰胺,例如γ-氨基丁酸易失水形成γ-丁内酰胺。γ-丁内酰胺又称四氢毗咯酮,它既具有微弱的碱性,能与盐酸形成盐酸盐;又具有微弱的酸性,能与氢氧化钠形成钠盐。γ-丁内酰胺进行烃化,可生成N-烃基四氢吡咯酮;与乙炔反应,生成N-乙烯基四氢吡咯酮,进一步聚合,生成聚乙烯基四氢吡咯酮。 工业上制造γ-丁内酰胺是用γ-丁内酯与氨在高温高压下反应制得;也可由丁二酰亚胺部分还原制得。δ-戊内酰胺又称六氢吡啶酮,可由δ-戊内酯与氨反应制得。小环内酰胺和大环内酰胺必须由间接方法制备,例如利用乙烯酮与亚胺加成可生成β-内酰胺;利用环酮肟的重排反应合成ε及更高级的内酰胺。 聚乙烯基四氢吡咯酮是血浆的代用品,是接受输血前的一种必要药物,也可作抗生素、局部麻醉药和激素等药物的延效赋形剂。在青霉素、头孢素等的结构中都含有β-内酰胺环。ε-己内酰胺是制造尼龙6纤维的原料。 |
说明:补充资料仅用于学习参考,请勿用于其它任何用途。
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