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1)  free radical seeded emulsion polymerization
自由基种子乳液聚合
1.
A free radical seeded emulsion polymerization model with the monomer partition was presented.
伴有水解缩合反应的自由基种子乳液聚合反应是制备有机-无机杂化乳胶粒的一种新方法,水解缩合反应和自由基聚合这两种反应在乳液体系中的动力学耦合过程决定了聚合产物的微结构和应用性质。
2)  free radical initiated emulsion polymerization
自由基引发乳液聚合
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3)  self-seed emulsion polymerization
自生种子乳液聚合
4)  Seeded emulsion polymerization
种子乳液聚合
1.
Synthesis of MCPU-PMMA hybrid emulsion through seeded emulsion polymerization;
种子乳液聚合制备MCPU-PMMA复合乳液
2.
Free radical seeded emulsion polymerization with participation of hydrolysis-condensation reaction(Ⅱ) Parameters and modeling application;
伴有水解缩合反应的种子乳液聚合动力学(Ⅱ) 参数求解和模型应用
3.
The highly cross-linked solid and hollow polymer particles which are poly(methyl methacrylate-co-divinylbenzene) were prepared by means of a seeded emulsion polymerization.
以种子乳液聚合法制备出具有空心结构的交联型乳胶粒,以低分子量的PS为种子,以MMA和DVB为壳单体对种子乳粒在高温下溶胀,由于种子聚合物和壳层聚合物之间相容性的不同,导致在壳层聚合时两者之间发生相分离,并在粒子内部产生空心结构。
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5)  seed emulsion polymerization
种子乳液聚合
1.
The results showed that the seed emulsion polymerization of styrene and butadiene in the presence of small size seed and batch addition of emulsifiers was a more(effective) route to synthesi.
采用种子乳液聚合法制备了丁苯共聚物/水泥复合材料专用丁苯胶乳,考察了复合乳化剂体系、种子胶乳用量、极性单体种类、聚合温度及加料方式等对乳胶粒尺寸及其分布和胶乳稳定性等的影响。
2.
Acrylic emulsion with core-shell structure,which can be used as the leather emulsion finishing agent,has been synthesized by use of pre-emulsion and seed emulsion polymerization technology.
采用预乳化工艺和种子乳液聚合的方法,合成了具有核壳结构的皮革用丙烯酸酯乳液。
3.
Multilayer latex particles with carboxylic polymer as core,polymer with low glass transition temperature and film-formable under room temperature as shell,and lightly crosslinked polymer as intermediate layer were prepared with unsaturated carboxylic monomers by multistage seed emulsion polymerization.
采用羧基单体进行多阶段的种子乳液聚合,制备了内核为带羧基的聚合物、最外层为易成膜的低玻璃化温度聚合物、中间为轻度交联中间隔离层的多层核壳结构乳胶粒,最后通过碱处理制成了具有室温成膜性的中空结构聚合物微粒。
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6)  seed-emulsion polymerization
种子乳液聚合
1.
Core/shell composite microparticles with silica nanoparticle as core and crosslinked poly(tert-butylmethacrylate) as shell were prepared by seed-emulsion polymerization utilizing 3-(trimethoxysilyl)propyl methacrylate(MPS) modified silica particles as seeds,tert-butylmethacrylate as monomer and sodium dodecyl sulfate(SDS) as emulsifier.
以甲基丙烯酸-3-(三甲氧基硅基)丙酯(MPS)修饰的SiO2胶体粒子为种子,甲基丙烯酸叔丁酯(tBMA)为单体、十二烷基硫酸钠(SDS)为乳化剂,采用种子乳液聚合法制备了SiO2/聚甲基丙烯酸叔丁酯的核壳复合微粒。
2.
The latex particles of St-BA/St-MMAVinylTriethoxylsilane core-shell structure were prepared by seed-emulsion polymerization and the properties of the emulsions and latex films were investigated.
通过种子乳液聚合法制备了以丙烯酸丁酯(BA)-苯乙烯(S t)共聚物为核,甲基丙烯酸甲酯(MM A)-苯乙烯(S t)-乙烯基三乙氧基硅烷(VTES)为壳的水性自交联乳液。
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补充资料：种子乳液聚合
分子式：
CAS号：

性质：又称种子(乳液)聚合，两阶段(或多阶段)乳液聚合，核-壳乳液聚合或复合乳液聚合。为了得到颗粒较大的聚合物，在乳液聚合中，可先加入乳液作为种子，这样在聚合过程中，单体可在加入的种子上继续聚合，而不形成新的微粒，因此可以得到颗粒较大的聚合物，这种聚合称为种子聚合。首先，通过常规的(一般为间歇式)乳液聚合或乳液共聚合制备种子胶乳，然后在种子胶乳存在下进行另一种单体或单体混合物的聚合。是新近发展起来的一种乳液聚合方法。主要用来合成各种具有不同组分以及不同形态特征的复合聚合物胶乳。

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