1)  α-bromination
α-溴代
2)  α-bromoketone
α-溴代酮
1.
6 were obtained from thioamides and α-bromoketones by a four-step reaction.
以硫代酰胺和α-溴代酮为原料,经4步反应合成了N,N′-二酰基肼(6),6在POCl3作用下脱水环化,合成了7个未见文献报道的2-芳基-5-[(4-芳基噻唑-2-基)甲基]-1,3,4-噁二唑类化合物,其结构经1H NMR,IR,MS和元素分析表征。
2.
Quinoxalines were obtained from α-bromoketones,1,2-diaminobenzene and DMSO in a solvent-free one-pot process at room temperature under grinding.
在室温无溶剂条件下,将α-溴代酮、邻苯二胺和二甲亚砜(DMSO)置于研钵中研磨,一锅法合成了一系列喹喔啉类化合物。
3.
On the basis of this, the additionreactions of N-sulfonylimines with α-bromoketones and α-bromoesters in the presentof zinc powder were carried out.
在此基础上又研究了α-溴代酮和α-溴代酯在金属锌的作用下与磺酰亚胺的加成反应。
3)  α-bromonaphthalene
α-溴代萘
1.
Non-Protected Fluid Room Temperature Phosphorescence of α-Bromonaphthalene;
α-溴代萘的无保护性介质流体室温燐光特性
2.
Studies on Effects of External Magnetic Field on the Formation Rate of Complex of α-Bromonaphthalene/β-Cycoldextrin and Different Aliphatic Alcohols by Kinetic Room-temperature Phosphorimetry;
动力学室温磷光法研究外磁场效应对不同脂肪醇/α-溴代萘/β-环糊精包络物生成速度的影响
3.
Room Temperature Phosphorescence Induced by Cyclodextrin of Carbaryl、α-Bromonaphthalene in the Presence of Small Organic Molecule and Its Application;
有机小分子存在下,环糊精诱导西维因、α-溴代萘室温磷光及其分析应用
4)  α-brominating
α溴代
5)  α-bromoaldehyde
α-溴代醛
1.
In organic synthesis α-bromoaldehydes are important media, which can be used to prepare α,β-unsaturated aldehydes and to stereoselectively synthesize a convenient bromizing agent-Dibromo Meldrum'sAcid (5, 5 -dibromo- 2, 2 - dimethyl - 4, 6 - dioxo - 1.
α-溴代醛是一种有用的有机合成中间体,主要用于制备α、β-不饱和醛和定向合成的光学活性异构体。
6)  α-bromoesters
α-溴代酯
1.
On the basis of this, the additionreactions of N-sulfonylimines with α-bromoketones and α-bromoesters in the presentof zinc powder were carried out.
在此基础上又研究了α-溴代酮和α-溴代酯在金属锌的作用下与磺酰亚胺的加成反应。
参考词条
补充资料:溴代乙酸
分子式:C2H3BrO2
分子量:138.96
CAS号:79-08-3

性质:无色结晶。熔点50℃,沸点208℃,相对密度1.93。易溶于水、乙醇、乙醚,可溶于丙酮和苯。有腐蚀性,易潮解。

制备方法:1.以醋酸为原料,在吡啶存在下滴加溴素进行反应制取之。2.由氯乙酸与氢溴酸反应而得。3.由羟乙酸与氢溴酸反应而得。

用途:有机合成中间体。用于农药和医药的生产中。还可生产其酯类。

说明:补充资料仅用于学习参考,请勿用于其它任何用途。