1) hyperbranched poly(phenylene oxide)
超支化聚苯醚
1.
Preparation and characterization of a novel fluorescent hyperbranched poly(phenylene oxide);
新型荧光超支化聚苯醚的合成与性能研究
2) hyperbranched PPS
超支化聚苯硫醚
1.
Investigation of hyperbranched PPS/PPS composite fiber shows that proper amount of hyperbranched PPS can increase the crystallinity of linear PPS;therefore tensile strength increases.
合成了3,4-二氯苯磺酰氯,用锌粉还原得到超支化聚苯硫醚(PPS)的单体——3,4-二氯硫酚,并用其制备了超支化PPS。
2.
Non-isothermal crystallization kinetics of hyperbranched PPS/PPS blend fiber was studied by differential scanning calorimetry (DSC).
使用DSC方法研究了聚苯硫醚(PPS)以及超支化聚苯硫醚/聚苯硫醚共混纤维的非等温结晶动力学,分析了结晶峰值温度等参数,并用Ozawa方程和莫志深方程描述了非等温动力学。
3) Hyperbranched polyether
超支化聚醚
1.
A novel hyperbranched PEU(PHEU) was synthesized by mixing hyperbranched polyether(PHEMO) with hexaethylene diisocyanate(HDI) in the electrolyte.
以双三氟甲基磺酸亚胺锂(LiTFSI)为溶质、三乙二醇双甲醚(TGE)为溶剂制备的电解液为介质,将超支化聚醚(PHEMO)与六次甲基二异氰酸酯(HDI)缩合生成了一种新型的超支化聚合物电解质(超支化聚氨酯,简称PHEU)。
2.
A series of aliphatic hyperbranched polyethers were synthesized by using the trimethylol propane as core molecule,and their molecular structures were characterized by IR,hydroxyl value.
合成了以三羟甲基丙烷为核的脂肪族超支化聚醚,并对其进行了红外表征,羟值测定。
3.
A novel kind of polymer electrolyte based on hyperbranched polyether was prepared,and its ionic conductivity was studied by electrochemical impedance spectroscopy(EIS).
合成一种新型超支化聚醚类固体聚合物电解质。
4) hyperbranched poly(ether ether ketone)
超支化聚醚醚酮
1.
Hydroxyl-terminated(HPEEK-OH) and fluoro-terminated(HPEEK-F) hyperbranched poly(ether ether ketone) were prepared from the mixture of hydroquinone(A_2) and 1,3,5-tris[4-(4-fluorobenzoyl)phenoxy]benzene(B_3) with different A_2/B_3 mass ratios.
进一步采用A2+B3法制备超支化聚醚醚酮,研究了端基对其热性能、溶液粘度特性的影响。
2.
Fluorin-terminated hyperbranched poly(ether ether ketone)(HPDEEK-F) was synthesized via A 2+B 3 reaction.
采用亲核取代反应,通过A2+B3方法制备含联苯结构氟封端超支化聚醚醚酮(HPDEEK-F),用4-苯乙炔苯酚与得到的氟封端聚合物反应,制得苯乙炔封端的超支化聚醚醚酮(HPDEEK-PEP),并研究了其结构和性能。
6) Hyperbranched poly(aryl ether ketone)s
超支化聚芳醚酮
1.
Hyperbranched poly(aryl ether ketone)s(HPETFDEK-F) were synthesized from the combination of 3,3′,5,5′,-tetramethyl biphenyl-4,4′-diol(A_2) and B_3,a novel monomer 1,3,5-tris[4-(4-flourobenzoyl)phenoxy] benzene synthesized in our lab.
用3-二甲氨基苯酚与超支化聚芳醚酮(HPETFDEK-F)的末端氟发生反应,制得荧光超支化聚芳醚酮(FHPETFDEK)。
补充资料:聚苯醚
| 聚苯醚 polyphenylene oxide 2,6-二甲基苯酚的聚合物。又称聚苯撑氧。英文缩写PPO。结构为 玻璃化温度约210℃ ,熔融温度257℃ ,密度0.96~1.06克/厘米3。实用聚苯醚的分子量为 2~5万,结晶度约 50%。最突出优点是高度耐水和耐蒸汽性。在 132 ℃的高压蒸汽容器内处理 200 次,抗拉和抗冲击强度没有显著变化,此外它还具有尺寸稳定性好 、蠕变小 、高绝缘性等特点 ,长期使用温度为-127~120℃,无负荷间断工作可达 200℃,与一般热固性塑料水平相当。聚苯醚由2,6-二甲基苯酚在铜盐 (如氯化亚铜)和胺的粘合催化剂作用下,在空气或纯氧中进行氧化偶合聚合而成。 聚苯醚易于加工成型,挤出、注射和模压均可。用于制造医疗器械代替不锈钢,能承受蒸汽消毒,也用于机械和电子零部件、绝缘材料等。聚苯醚与聚苯乙烯共混改性物在美国商品名Noryl,并可加20%~30% 玻璃纤维、碳纤维等增强,是一种性能优良的工程塑料和绝缘材料。 |
说明:补充资料仅用于学习参考,请勿用于其它任何用途。
参考词条
玻璃化温度约210℃ ,熔融温度257℃ ,密度0.96~1.06克/厘米