1) iridium(Ⅲ)complex
铱Ⅲ配合物
2) Iridium(Ⅲ) complex
铱(Ⅲ)配合物
1.
Red single crystals of an iridium(Ⅲ) complex,[(btfmp)2Ir(dbm)](btfmp=2-(benzo[b]thio-phen-2-yl)-5-(trifluoromethyl)pyridine,dbm=dibenzoylmethane),were grown from sublimation,and characterized by elemental analysis,NMR,Ms,IR and single-crystal X-ray diffraction.
通过升华法生长出铱(Ⅲ)配合物(btfmp)2Ir(dbm)(btfmp=2-苯并噻吩-5-三氟甲基吡啶,dbm=二苯甲酰甲烷)红色单晶,并对其进行了元素分析、核磁、质谱、红外光谱表征及X射线单晶衍射测试。
3) Iridium pyrazine complex
吡嗪铱(Ⅲ)配合物
4) Aqua-chloroiridate(Ⅲ)complexes
铱(Ⅲ)氯水配合物
5) Cyclometalated Ir(Ⅲ)complex
环状金属铱(Ⅲ)配合物
6) iridium complex
铱配合物
1.
A bis-cyclometalated iridium complex (ffbi)2Ir(acac) (ffbi=1-(4-fluorobenzyl)-2-(4-fluorophenyl)benzimid-azole, acac=acetylacetone) containing benzimidazole-based ligand has been synthesized and used as an emitter in organic light emitting diodes (OLEDs).
合成了一种含苯并噻唑结构配体的环金属化铱配合物(ffbi)2Ir(acac),(其中ffbi为1-(4-氟苄基)-2-(4-氟苯基)苯并咪唑,acac为乙酰丙酮),并以其作为发光体,制备了有机电致发光器件。
2.
The present paper deals with the preparation and characterization of new tris-cyclometalated iridium complexes with p-substituted-2-phenylbenzothiazol ligands.
合成并表征了配体为苯并噻唑衍生物的2种新型铱配合物,三[N,N-二(4甲苯基)-4-(2-苯并噻唑基)苯胺]合铱(Ir(bpmp)3)和三[N,N-二苯基-4(-2-苯并噻唑基)苯胺]合铱(Ir(bpp)3)。
3.
A new blue-green light-emitting iridium(Ⅲ)bis(1-phenylpyridine)(1,2,4-triazole pyridine)complex was synthesized by the reaction of 1-phenylpyridine,1,2,4-triazole pyridine and iridium trichloride hydrate,which expanded the choice range of blue-light iridium complexes effectively.
利用1-苯基吡唑、吡啶三唑与水合三氯化铱反应合成了一种新型铱配合物Ir(2N)2(PZ),研究了配合物的吸收光谱、光致发光光谱以及光致发光效率。
补充资料：铱(iridium)
【铱】(iridium)化学元素[周期系第VIII族（类）元素]。符号`Ir`。原子序数77，原子量192.22。基态电子构型`1s^22s^22p^63s^23p^63d^104s^24p^6``4d^104f^145s^25p^65d^76s^2`。常见化合价3、4。自然界有两种稳定同位素`_77^197Ir`、`_77^193Ir`，另有三十种放射性同位素。银白色金属。性硬而脆。比重22.42（17℃）。熔点2，4
说明：补充资料仅用于学习参考，请勿用于其它任何用途。
参考词条