1) solid phase synthesis
固相合成
1.
A microwave-irradiation technique was applied to the solid phase synthesis of thymopentin,and also the influences of coupling reagents,solvents,reactant concentration,reaction time and temperature on the solid phase synthesis yield of thymopentin with microwave irradiation were investigated.
在胸腺五肽的固相合成中,引入微波辅助技术,深入研究了微波作用下缩合试剂、溶剂、反应物浓度、反应时间和温度对产率的影响。
2.
And sansalvamide A was obtained by solid phase synthesis using Py- BOP (benzotriazole-1-yl-oxy-tris-pyrrolidino-phosphonium hexafluorophosphate) as cyclization reagent.
报道了Pd催化丁基二乙基硅烷树脂与N-Boc-4-溴代苯丙氨酸甲酯直接反应形成Si—Ar键一步构建出硅基连接分子的新方法,并采用Boc策略增长肽链,以PyBOP(benzotriazole-1-yl-oxy-tris-pyrrolidino-phosphoniumhexafluoro-phosphate)为环合剂固相合成了sansalvamideA。
3.
This paper with 29 references reviewed the design, synthesis and applications of organosilyl linkers in solid phase synthesis within 26.
固相合成方法具有传统液相反应无可比拟的优越性 ,已被越来越多的化学家认可。
2) solid-phase synthesis
固相合成
1.
Fmoc solid-phase synthesis of MSH peptide;
Fmoc固相合成法合成黑色素细胞刺激素(MSH)的工艺研究
2.
The Solid-Phase Synthesis and Characterization of Transition Metal Complex with 1,6-Hexanediamine Schiff Base;
过渡金属1,6-己二胺缩双水杨醛Schiff碱配合物的固相合成与表征
3.
The solid-phase synthesis of (o-vanillin)-p-toluidine and its complex with copper acetate;
邻香兰素缩对甲苯胺及其醋酸铜配合物的固相合成
3) solid state synthesis
固相合成
1.
[Cu{OC(NH-2)-2}-4]Cl-2 and [Cu{OC(NH-2)-2}-4]SO-4 were synthesized by the room tempreature solid state synthesis with the material of copper trichloride or cupric sulfate and urea.
分别以氯化铜、硫酸铜和尿素为原料、通过室温固相合成法得到了[Cu{OC(NH2)2}4]Cl2和[Cu{OC(NH2)2}4]SO4两种固相配合物。
2.
After comparing many synthesis methods, we have developed an improved method of solid state synthesis to prepare zinc oxide nanoparticles.
在比较了各种合成方法后,我们采用固相合成法来制备纳米氧化锌,并对其提出了改进。
3.
Aluminum phosphate (AlPO 4) can be prepared by solid state synthesis with different templates (organic ammonium), aluminum chloride and ammonium diacid phosphate at low temperature (180℃) within a short time (2 h).
以氯化铝和磷酸二氢铵为原料 ,在模板剂存在下用固相合成方法合成了磷酸铝类化合物 ,合成的化合物通过化学分析、ICP测定、XRD和 IR图谱对其进行了表征 ,研究了化合物对铬离子吸附性能 ,实验表明这类化合物对铬离子有较好的吸附能
4) solid-state synthesis
固相合成
1.
Electrochemical properties of Nb doped LiFePO_4/C prepared by one-step solid-state synthesis;
一步固相合成Nb掺杂LiFePO_4/C及其电化学性能
2.
The experimental results has indicated that zinc incorporated aluminum phosphate compounds(ZnAlPO_4) could be prepared by solid-state synthesis in the presence of template from aluminum chloride,ammonium dihydric phosphate and zinc chloride at low temperature(180°C) and in short time(2 hours).
用固相合成方法,在模板剂存在下,以结晶氯化铝、磷酸二氢铵和适量的醋酸锌为原料,合成了含金属元素锌的磷酸铝类化合物,合成的化合物通过元素的化学分析和ICPS测定、XRD和IR图谱,确定其元素的组成,并对产物进行了表征。
3.
5H3PMo12O40·H2O is synthesized by solid-state synthesis based on the reaction of acridine orange and molybdphosphoric acid of Keggin structure at room temperature.
以Keggin结构磷钼酸和吖啶橙为原料,采用室温固相合成法合成一种新型电荷转移配合物[C17H19N3]2。
5) solid state reaction
固相合成
1.
Characterization and preparation of nanometersized KMn_8O_(16) by solid state reaction at room temperature;
纳米KMn_8O_(16)粉体的室温固相合成与表征
2.
Study on synthetic conditions of glucogalactane by solid state reactions under microwave irradiation;
微波固相合成葡-半乳低聚糖的工艺研究
3.
Transition metal complexes of hexamethylene tetramine are synthesized by solid state reaction and their thermochromism is investigated by TG-DSC spectra.
研究了六次甲基四胺的过渡金属配合物的固相合成及其热色性。
6) solid-state reaction
固相合成
1.
This paper reviews the structure and properties of Li_4Ti_5O_ 12 and explores researches at home and broad from the aspects of preparation method(sol-gel,solid-state reaction,etc.
本文介绍了Li4Ti5O12的结构和性能;从制备方法(溶胶-凝胶法、固相合成法等)、掺杂改性和与其他材料复合等几个方面介绍了国内外关于Li4Ti5O12的制备和改性方面的研究进展;并对Li4Ti5O12在各种器件中的应用研究进展做了介绍。
2.
15) as cathode for lithium-ion batteries were fabricated by high temperature solid-state reaction method.
采用高温固相合成法制备了LiMn2O4、Ni和Cr以及Ni-Cr复合掺杂的锂离子电池用锰酸锂正极材料。
补充资料：固相合成法
分子式：
CAS号：
性质：使用不溶性高聚物为载体，通过其活性基团将反应物之一固定在高分子载体上，使有机合成在固相上进行的方法。如用氯甲基化苯乙烯-二乙烯基苯共聚物作载体，使氨基酸依次缩合，将链不断延长下去，用这种方法能够合成具有任意单体序列的多肽。
CAS号：
性质：使用不溶性高聚物为载体，通过其活性基团将反应物之一固定在高分子载体上，使有机合成在固相上进行的方法。如用氯甲基化苯乙烯-二乙烯基苯共聚物作载体，使氨基酸依次缩合，将链不断延长下去，用这种方法能够合成具有任意单体序列的多肽。
说明：补充资料仅用于学习参考，请勿用于其它任何用途。
参考词条